Nickel-Catalyzed Desulfonylative Reductive Cross-Coupling of Aryl Sulfones with Aryl Bromides

被引：13

作者：

Huang, Xinmiao ^{[1
,2
]}

Tang, Ling ^{[1
,2
]}

Song, Zhiyong ^{[1
,2
]}

Jiang, Shuangshuang ^{[1
,2
]}

Liu, Xianmao ^{[1
,2
]}

Ma, Ming ^{[1
,2
]}

Chen, Bo ^{[1
,2
]}

Ma, Yuanhong ^{[1
,2
]}

机构：

[1] Hunan Normal Univ, Coll Chem & Chem Engn, Key Lab Phytochemistry R&D Hunan Prov, Key Lab Chem Biol & Tradit Chinese Med Res,Minist, Changsha 410081, Peoples R China

[2] Hunan Normal Univ, Coll Chem & Chem Engn, Key Lab Assembly & Applicat Organ Funct Mol Hunan, Changsha 410081, Peoples R China

来源：

ORGANIC LETTERS | 2023年

基金：

中国国家自然科学基金;

关键词：

SULFIDES; HALIDES; BONDS;

D O I：

10.1021/acs.orglett.3c00185

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Herein, a nickel catalysis system for desulfonylative C(sp(2))-C(sp(2)) reductive cross-coupling reactions of aryl sulfone derivatives with a range of aryl bromides has been established to form diverse biaryl compounds. The complex Ar-Ni(II)-SO(2)CF3 bearing a phosphine ligand through oxidative addition of aryl sulfone to Ni(0) species was isolated and confirmed by an X-ray, which provides solid evidence for the understanding of the C(Ar)-SO2 bond activation and reaction mechanism.

引用

收藏

页码：1198 / 1203

页数：6

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