Recent advances in two-dimensional polymers: synthesis, assembly and energy-related applications

被引:17
作者
Ren, Yumei [1 ,2 ]
Xu, Yuxi [1 ]
机构
[1] Westlake Univ, Sch Engn, Hangzhou 310024, Zhejiang, Peoples R China
[2] Zhengzhou Univ Aeronaut, Sch Mat Sci & Engn, Zhengzhou 450046, Peoples R China
基金
中国国家自然科学基金;
关键词
COVALENT ORGANIC FRAMEWORKS; CONJUGATED MICROPOROUS POLYMERS; ON-SURFACE POLYMERIZATION; MONOLAYER SHEET; SINGLE-CRYSTAL; NANOSHEETS; GRAPHENE; NANOMATERIALS; DELAMINATION; EXFOLIATION;
D O I
10.1039/d3cs00782k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two-dimensional polymers (2DPs) are a class of 2D crystalline polymer materials with definite structures, which have outstanding physical-chemical and electronic properties. They cleverly link organic building units through strong covalent bonds and can construct functional 2DPs through reasonable design and selection of different monomer units to meet various application requirements. As promising energy materials, 2DPs have developed rapidly in recent years. This review first introduces the basic overview of 2DPs, such as their historical development, inherent 2D characteristics and diversified topological advantages, followed by the summary of the typical 2DP synthesis methods recently (including "top-down" and "bottom-up" methods). The latest research progress in assembly and processing of 2DPs and the energy-related applications in energy storage and conversion are also discussed. Finally, we summarize and prospect the current research status, existing challenges, and future research directions of 2DPs. This review summarizes the advancements of 2D polymers and highlights their unique advantages, focusing on their recent research progress in the design, synthesis, assembly and processing, as well as their energy-related applications.
引用
收藏
页码:1823 / 1869
页数:47
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