Fe(OTf)3-Catalyzed Synthesis of Boronic Ester Containing N,O-Acetal Structure

被引：0

作者：

Lu Min ^{[1
,2
]}

Yang Aimei ^{[1
]}

Zhang Yu ^{[1
,2
]}

Sun Jianting ^{[2
]}

Wei Bangguo ^{[2
]}

机构：

[1] Lanzhou Univ Technol, Sch Life Sci & Engn, Lanzhou 730050, Peoples R China

[2] Fudan Univ, Sch Pharm, Shanghai 201203, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 43卷 / 05期

基金：

中国国家自然科学基金;

关键词：

iminonium; N; O-acetal; boronic ester; addition reaction; CROSS-COUPLING REACTION; REGIOSELECTIVE GLYCOSYLATION; ASYMMETRIC-SYNTHESIS; IXAZOMIB CITRATE; TRANSESTERIFICATION; DERIVATIVES; CHEMISTRY; ACIDS;

D O I：

10.6023/cjoc202301017

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A convenient approach acess to boronic ester containing N,O-acetal structure has been established through the Fe(OTf)(3)-catalyzed addition of N,O-acetal with organic boric acid. A series of N-O-acetal boronic ester compounds have been successfully prepared in 58%similar to 98% yields. Moreover, these compounds retain the property of boronic ester and can be used for coupling reaction.

引用

页码：1777 / 1785

页数：9

共 64 条

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