Palladium-Catalyzed Unimolecular Fragment Coupling of N -Allylamides Bearing a Tethered Nucleophile with the Translocation of an Amide Group

被引：5

作者：

Shimazumi, Ryoma ^{[1
]}

Kodama, Takuya ^{[1
,2
]}

Tobisu, Mamoru ^{[1
,2
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

[2] Osaka Univ, Inst Open & Transdisciplinary Res Initiat ICS OTRI, Innovat Catalysis Sci Div, Suita, Osaka 5650871, Japan

来源：

SYNTHESIS-STUTTGART | 2023年 / 56卷 / 01期

基金：

日本科学技术振兴机构; 日本学术振兴会;

关键词：

palladium catalyst; C-N bond activation; amides; isocyanates; elimination; rearrangement; ALKENES; BONDS;

D O I：

10.1055/a-2022-1905

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The palladium-catalyzed reaction of N-allylamides bearing a tethered nucleophile results in the extrusion of an amide moiety in the form of an isocyanate, with its subsequent capture by the pendant nucleophile. This reaction involves the net catalytic transposition of an amide group.

引用

页码：134 / 142

页数：9

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