Hollow spheres constructed by ZnS-CoS2 @N-doped carbon@N-doped carbon as anodes for high-performance sodium-ion batteries

被引:11
作者
He, Haishan [1 ,2 ]
Li, Mingquan [1 ,2 ]
Gan, Yunfei [1 ,2 ]
Mou, Jirong [2 ]
Yuan, Jujun [2 ]
Zhang, Xianke [2 ]
Li, Bin [3 ]
Yu, Jing [2 ]
Zhang, Chao [2 ]
Li, Xiaokang [1 ,2 ]
Liu, Jun [2 ,4 ]
机构
[1] Gannan Normal Univ, Coll Chem & Chem Engn, Ganzhou 341000, Peoples R China
[2] Gannan Normal Univ, Sch Phys & Elect, Ganzhou 341000, Peoples R China
[3] Ganzhou Jirui New Energy Technol Co Ltd, Ganzhou 341000, Peoples R China
[4] South China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510641, Peoples R China
关键词
ZnS; CoS2; Hollow spheres; N-doped Carbon; Sodium ion battery; Anode; STORAGE; LITHIUM;
D O I
10.1016/j.jallcom.2024.173606
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Hollow spheres constructed by ZnS-CoS2 @N-doped Carbon@N-doped carbon (ZnS-CoS2 @NC@NC) are successfully synthesized using template method combined with NC coating procedure. For SIBs anode, ZnS-CoS2 @NC@NC electrode exhibits excellent rate property and sustainable capacity of 164 mAh g-1 at 5 A g-1 after 1000 cycles. The superior sodium storage performance for ZnS-CoS2 @NC@NC composites is benefited from its distinctive structure, in which the hollow architecture for ZnS/CoS2 @NC@NC composites can buffer the volume change of ZnS/CoS2 and enhance electronic/ionic conductivity within charge/discharge processes. Furthermore, the NC shell layer can further alleviate structural degradation of ZnS/CoS2 @NC@NC hollow spheres, and supply more effective active sites.
引用
收藏
页数:7
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