Structural stability and proton beam irradiation effects on simulated metal fluoride waste-loaded iron phosphate glass

被引：2
作者：
Joshi, Akhilesh C. [1 ,2 ]
Roy, Mainak [1 ,2 ]
Dutta, Dimple P. [1 ,2 ]
Mishra, Raman K. [3 ]
Meena, Sher Singh [4 ]
Kumar, Ravi [5 ]
机构：
[1] Bhabha Atom Res Ctr, Chem Div, Mumbai 400085, India
[2] Homi Bhabha Natl Inst, Mumbai, India
[3] Bhabha Atom Res Ctr, Waste Management Div, Mumbai, India
[4] Bhabha Atom Res Ctr, Solid State Phys Div, Mumbai, India
[5] Bhabha Atom Res Ctr, Atom & Mol Phys Div, Mumbai, India
来源：
INTERNATIONAL JOURNAL OF APPLIED GLASS SCIENCE | 2024年 / 15卷 / 03期
关键词：
fluoride loading; iron phosphate glass; nuclear waste vitrification; proton irradiation; FORMING ABILITY; MOSSBAUER-SPECTROSCOPY; REACTOR WASTE; FE; ENVIRONMENT; MO;
D O I：
10.1111/ijag.16658
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Next-generation nuclear reactor technologies such as the molten salt reactor utilize alkali metal fluoride salts as both fuel and coolant. In the present study, the suitability of iron phosphate glass (IPG) as a vitrification matrix for alkali metal fluoride (NaF, CaF2) and simulated fission product loaded fluoride (NdF3, CeF3, SmF3) waste has been explored. The structural change in the metal fluoride-loaded IPG has been analyzed thoroughly using Raman and fourier transform infrared (FTIR) spectroscopy. Thermal analysis showed that the stability and glass forming ability of IPG improved upon loading the same with various mixed metal fluorides. Mossbauer data and X-ray absorption spectroscopy at Fe K-edge explored the minute changes in the local structure. The effect of radiation emanating from radioactive wastes in the fluoride-loaded IPG has been scrutinized via 4.5 MeV proton beam irradiation. Our study firmly establishes the applicability of IPG as suitable vitrification matrix for radioactive metal fluoride-loaded nuclear wastes.
引用
收藏
页码：292 / 306
页数：15
相关论文
共 42 条
  • [1] The structure and properties of cesium loaded Mo-Fe-phosphate glasses
    Bai, Jincheng
    Hsu, Jenhsien
    Sandineni, Prashanth
    Kim, Cheol-Woon
    Brow, Richard K.
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 2019, 510 : 121 - 129
  • [2] A comprehensive facility for EXAFS measurements at the INDUS-2 synchrotron source at RRCAT, Indore, India
    Basu, S.
    Nayak, C.
    Yadav, A. K.
    Agrawal, A.
    Poswal, A. K.
    Bhattacharyya, D.
    Jha, S. N.
    Sahoo, N. K.
    [J]. 17TH PAN-AMERICAN SYNCHROTRON RADIATION INSTRUMENTATION CONFERENCE SRI2013, 2014, 493
  • [3] Effects of modifier additions on the thermal properties, chemical durability, oxidation state and structure of iron phosphate glasses
    Bingham, P. A.
    Hand, R. J.
    Hannant, O. M.
    Forder, S. D.
    Kilcoyne, S. H.
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 2009, 355 (28-30) : 1526 - 1538
  • [4] Boroica L, 2013, J OPTOELECTRON ADV M, V15, P187
  • [5] Ab initio molecular dynamics simulations of structural changes associated with the incorporation of fluorine in bioactive phosphate glasses
    Christie, Jamieson K.
    Ainsworth, Richard I.
    de Leeuw, Nora H.
    [J]. BIOMATERIALS, 2014, 35 (24) : 6164 - 6171
  • [6] Chemically durable iron phosphate glass wasteforms
    Day, DE
    Wu, Z
    Ray, CS
    Hrma, P
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 1998, 241 (01) : 1 - 12
  • [7] Structural investigations on Mo, Cs and Ba ions-loaded iron phosphate glass for nuclear waste storage application
    Dutta, Dimple P.
    Roy, Mainak
    Mishra, Raman K.
    Meena, Sher Singh
    Yadav, A.
    Kaushik, C. P.
    Tyagi, A. K.
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2021, 850
  • [8] Mossbauer spectroscopy of earth and planetary materials
    Dyar, M. Darby
    Agresti, David G.
    Schaefer, Martha W.
    Grant, Christopher A.
    Sklute, Elizabeth C.
    [J]. ANNUAL REVIEW OF EARTH AND PLANETARY SCIENCES, 2006, 34 : 83 - 125
  • [9] Iron redox equilibrium, structure and properties of iron phosphate glasses
    Fang, XY
    Ray, CS
    Mogus-Milankovic, A
    Day, DE
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 2001, 283 (1-3) : 162 - 172
  • [10] Ab initio and experimental pre-edge investigations of the Mn K-edge XANES in oxide-type materials -: art. no. 155109
    Farges, F
    [J]. PHYSICAL REVIEW B, 2005, 71 (15)
12345