Thickness-dependent thermoelectric properties of ultrathin polymer film on self-assembled monolayers

Conductive polymers have attracted attention for wearable and implantable thermoelectric devices due to their lightweight, flexibility, and solubility. With the development of microsystems, thermoelectric power generation devices are trending toward miniaturization, flexibility, high integration, and lightweight thin films. Therefore, the study of the thickness of thermoelectric materials has become increasingly important. In this study, we prepared ultrathin polymer thermoelectric (TE) films with different thicknesses (14-52 nm) by modifying the substrate with self-assembled monolayers (SAMs). The thickness-dependent thermoelectric performances on SAMs are investigated. It is found that SAMs regulate the carrier concentration in polymer ultrathin TE films, and a smoother surface contributes to the improvement of carrier mobility, thus optimizing the thermoelectric performance. The maximum modulation of thermoelectric performance is observed at a film thickness of approximately 35 nm, which contains nine molecular layers.