Experimental investigation on the effect of interfacial properties of chemical flooding for enhanced heavy oil recovery

被引:30
作者
Cao, Han [1 ,2 ]
Li, Yiqiang [1 ,2 ]
Gao, Wenbin [3 ]
Cao, Jinxin [1 ,2 ]
Sun, Bingyu [4 ]
Zhang, Jin [5 ]
机构
[1] China Univ Petr, State Key Lab Petr Resources & Prospecting, Beijing 102249, Peoples R China
[2] China Univ Petr, Coll Petr Engn, Beijing 102249, Peoples R China
[3] Chinese Acad Sci, Inst Rock & Soil Mech, State Key Lab Geomech & Geotech Engn, Wuhan 430071, Peoples R China
[4] China Univ Petr East China, Sch Petr Engn, Qingdao 266580, Peoples R China
[5] PetroChina, Dagang Oilfield Co, Res Inst Explorat & Dev, Tianjin 300280, Peoples R China
基金
中国国家自然科学基金;
关键词
Heavy oil; Polymer flooding; Surfactant flooding; Pores scale; Enhanced oil recovery; EMULSIFICATION; ASPHALTENE; TENSION; ACIDS;
D O I
10.1016/j.colsurfa.2023.132335
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Chemical compound flooding has demonstrated its efficacy in enhancing light oil recovery through ultra-low interfacial tension (IFT). However, the optimization of chemical systems properties for displacing heavy oil has not been clarified. This research aims to address this problem by designing common polymer and three surfactant-polymer (SP) systems with varying IFT and interfacial viscoelasticity behaviors, and comparing their ability to recover heavy oil. The findings of core flooding tests indicate that the system with low IFT and high interfacial viscoelasticity simultaneously has a better displacement efficiency for heavy oil than other flood systems, which could enhance heavy oil recovery by 21.94%. Micro-model tests reveal the underlying mechanisms driving the enhanced macro-scale oil recovery. The emulsion formation and interface expansion facilitated by low IFT, as well as increased emulsion stability and reduced snap-off of oil droplets due to the presence of an elastic oil-water interfacial film. These phenomena is more capable of driving microscopic heterogeneous remaining oil and film remaining oil than other solution. The comparative experiment analysis shows that the difference in chemical flooding between heavy oil and light oil is caused by the discrepant distributions of surfactants at the oil-water interface. The light oil interface is a monolayer surfactant molecular film, the heavy components and surfactant moleculars exhibit both competitive and cooperative adsorption phenomena at the oil-water interface. The occurrence of viscosity reduction and increased emulsion stability are more influential factors in the process of heavy oil displacement than those of conventional ultra-low IFT systems used for light oil recovery.
引用
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页数:12
相关论文
共 43 条
[1]   Polymeric surfactants for enhanced oil recovery: A review of recent progress [J].
Afolabi, Funsho ;
Mahmood, Syed M. ;
Yekeen, Nurudeen ;
Akbari, Saeed ;
Sharifigaliuk, Hamid .
JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING, 2022, 208
[2]   Interfacial and molecular interactions between fractions of heavy oil and surfactants in porous media: Comprehensive review [J].
Ahmadi, Mohammadali ;
Hou, Qingfeng ;
Wang, Yuanyuan ;
Chen, Zhangxin .
ADVANCES IN COLLOID AND INTERFACE SCIENCE, 2020, 283
[3]   Water flooding of oil reservoirs: Effect of oil viscosity and injection velocity on the interplay between capillary and viscous forces [J].
Arab, Danial ;
Kantzas, Apostolos ;
Bryant, Steven L. .
JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING, 2020, 186
[4]   The viscosifying behavior of W/O emulsion and its underlying mechanisms: Considering the interfacial adsorption of heavy components [J].
Cao, Changxiao ;
Gu, Shaohua ;
Song, Zhaojie ;
Xie, Zehui ;
Chang, Xuya ;
Shen, Pingping .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2022, 632
[5]   Visualized investigation of the immiscible displacement: Influencing factors, improved method, and EOR effect [J].
Chen, Xin ;
Li, Yiqiang ;
Liu, Zheyu ;
Trivedi, Japan ;
Tang, Yongqiang ;
Sui, Mingyue .
FUEL, 2023, 331
[6]   A comparative study of the mechanism and performance of surfactant- and alkali-polymer flooding in heavy-oil recovery [J].
Ding, MingChen ;
Wang, Yefei ;
Yuan, Fuqing ;
Zhao, Hailong ;
Li, Zongyang .
CHEMICAL ENGINEERING SCIENCE, 2020, 219
[7]   The role of IFT and emulsification in recovering heavy oil during S/SP flooding [J].
Ding, MingChen ;
Wang, Yefei ;
Li, Zongyang ;
Zhong, Dong ;
Yuan, Fuqing ;
Zhu, Yangwen .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2019, 77 :198-208
[8]   Synthesis, interfacial activity and rheological properties of low interfacial tension viscoelastic Gemini surfactants [J].
Feng, Shuyun ;
Jiang, Zhaowen ;
Tang, Shanfa ;
Hu, Ruizhi ;
Jin, Lijun ;
Wang, Siyao ;
Wang, Rui .
JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING, 2022, 209
[9]   Effect of surfactant on pore-scale mobilization characteristics in various pore structure conglomerate for enhanced oil recovery [J].
Gao, Wenbin ;
Li, Yiqiang ;
Zhang, Jin ;
Luan, Huoxin ;
Cao, Han ;
Yu, Zhihao .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2021, 627
[10]   Effects of asphaltenes and organic acids on crude oil-brine interfacial visco-elasticity and oil recovery in low-salinity waterflooding [J].
Garcia-Olvera, Griselda ;
Reilly, Teresa M. ;
Lehmann, Teresa E. ;
Alvarado, Vladimir .
FUEL, 2016, 185 :151-163