C-H functionalization with alkenes, allenes, and alkynes by half- sandwich rare-earth catalysts

被引：37

作者：

Cong, Xuefeng ^{[1
]}

Huang, Lin ^{[1
]}

Hou, Zhaomin ^{[1
,2
]}

机构：

[1] RIKEN Ctr Sustainable Resource Sci, Adv Catalysis Res Grp, 2-1 Hirosawa, Wako, Saitama 3510198, Japan

[2] RIKEN Cluster Pioneering Res, Organometall Chem Lab, 2-1 Hirosawa, Wako, Saitama 3510198, Japan

来源：

TETRAHEDRON | 2023年 / 135卷

关键词：

C-H activation; Asymmetric catalysis; C-C bond Formation; Half-sandwich rare-earth catalyst; Annulation; TERMINAL ALKYNES; AROMATIC IMINES; BOND ADDITION; STYRENE POLYMERIZATION; OLEFIN POLYMERIZATION; INTERMOLECULAR 2+2; METHYL SULFIDES; METAL COMPLEXES; SCANDIUM; ALKYLATION;

D O I：

10.1016/j.tet.2023.133323

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Catalytic C-H activation and transformation has received tremendous attention. This Perspective focuses on recent advances in C-H functionalization with alkenes, allenes, and alkynes by half-sandwich rare-earth catalysts, including asymmetric transformations. The reaction generally proceeds through formal C-H addition to unsaturated C-C bonds, thus constituting a 100% atom-efficient route for the con-struction of new C-C bonds. Future outlooks in related areas are also described. (c) 2023 Elsevier Ltd. All rights reserved.

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页数：16

相关论文

共 121 条

[91] Highly efficient and enantioselective cyclization of aromatic imines via directed C-H bond activation [J].

Thalji, RK ;

Ellman, JA ;

Bergman, RG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (23) :7192-7193

[92] Annulation of aromatic imines via directed C-H activation with Wilkinson's catalyst [J].

Thalji, RK ;

Ahrendt, KA ;

Bergman, RG ;

Ellman, JA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (39) :9692-9693

[93] ALPHA-BOND METATHESIS FOR C-H BONDS OF HYDROCARBONS AND SC-H, SC-ALKYL, SC-ARYL BONDS OF PERMETHYLSCANDOCENE DERIVATIVES - EVIDENCE FOR NONINVOLVEMENT OF THE PI-SYSTEM IN ELECTROPHILIC ACTIVATION OF AROMATIC AND VINYLIC C-H BONDS [J].

THOMPSON, ME ;

BAXTER, SM ;

BULLS, AR ;

BURGER, BJ ;

NOLAN, MC ;

SANTARSIERO, BD ;

SCHAEFER, WP ;

BERCAW, JE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (01) :203-219

[94] SOME ASPECTS OF THE CHEMISTRY OF ALKYL AND HYDRIDE DERIVATIVES OF PERMETHYLSCANDOCENE [J].

THOMPSON, ME ;

BERCAW, JE .

PURE AND APPLIED CHEMISTRY, 1984, 56 (01) :1-11

[95] Rhodium(III)-Catalyzed Arylation of Boc-Imines via C-H Bond Functionalization [J].

Tsai, Andy S. ;

Tauchert, Michael E. ;

Bergman, Robert G. ;

Ellman, Jonathan A. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (05) :1248-1250

[96] Rhodium catalyzed enantioselective cyclization of substituted imidazoles via C-H bond activation [J].

Tsai, Andy S. ;

Wilson, Rebecca M. ;

Harada, Hitoshi ;

Bergman, Robert G. ;

Ellman, Jonathan A. .

CHEMICAL COMMUNICATIONS, 2009, (26) :3910-3912

[97] Direct functionalization of unactivated C-H bonds catalyzed by group 3-5 metal alkyl complexes [J].

Tsurugi, Hayato ;

Yamamoto, Koji ;

Nagae, Haruki ;

Kaneko, Hiroshi ;

Mashima, Kazushi .

DALTON TRANSACTIONS, 2014, 43 (06) :2331-2343

[98] Coordinative Chain Transfer Polymerization [J].

Valente, Andreia ;

Mortreux, Andre ;

Visseaux, Marc ;

Zinck, Philippe .

CHEMICAL REVIEWS, 2013, 113 (05) :3836-3857

[99]

Wahl M., 2018, ANGEW CHEM INT EDIT, V57, P4647

[100] Theoretical Studies of Rare-Earth-Catalyzed [3+2] Annulation of Aromatic Aldimine with Styrene: Mechanism and Origin of Diastereoselectivity [J].

Wang, Pan ;

Luo, Gen ;

Yang, Jimin ;

Cong, Xuefeng ;

Hou, Zhaomin ;

Luo, Yi .

JOURNAL OF ORGANIC CHEMISTRY, 2021, 86 (05) :4236-4244

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