Sustainable energy storage: Mangifera indica leaf waste-derived activated carbon for long-life, high-performance supercapacitors

被引:35
作者
Hegde, Shreeganesh Subraya [1 ]
Bhat, Badekai Ramachandra [1 ]
机构
[1] Natl Inst Technol Karnataka, Dept Chem, Catalysis & Mat Chem Lab, Mangalore 575025, Karnataka, India
关键词
HIERARCHICAL POROUS CARBON; TEMPERATURE; BIOMASS; NANOSHEETS; TEMPLATE;
D O I
10.1039/d3ra08910j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Biomass waste-derived activated carbon has a wide range of applications, including air and water purification, gas separation, energy storage, and catalysis. This material has become increasingly popular in recent years as a result of the growing demand for sustainable and eco-friendly materials. In this study, Mangifera indica leaf waste-derived activated carbon has been investigated as an electrode material for high-performance supercapacitors. The dried Mangifera indica leaves were first carbonized using FeCl3 and then activated using KOH to increase their surface area and pore structure at different temperatures. The activated carbon prepared at 725 degrees C has shown a high specific capacitance of 521.65 F g(-1) at a current density of 0.5 A g(-1) and also achieved an energy density of 17.04 W h kg(-1) at a power density of 242.50 W kg(-1) in the 6 M KOH electrolyte. Significantly, it has demonstrated remarkable electrochemical cycling stability, retaining 96.60% of its initial capacity even after undergoing 10 001 cycles at a scan rate of 500 mV s(-1). The superior electrochemical performance of the activated carbon can be attributed to its high surface area of 1232.63 m(2) g(-1), well-distributed pore size, and excellent degree of graphitization, which all facilitate the rapid diffusion of ions and enhance the accessibility of the electrolyte to the electrode surface. Hence, this study provides a promising route for utilizing waste biomass as a low-cost, sustainable electrode material for energy storage devices.
引用
收藏
页码:8028 / 8038
页数:11
相关论文
共 44 条
[1]   Biomass to porous carbon in one step: directly activated biomass for high performance CO2 storage [J].
Balahmar, Norah ;
Al-Jumialy, Abdul Salam ;
Mokaya, Robert .
JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (24) :12330-12339
[2]   Biomass-derived porous carbon materials with different dimensions for supercapacitor electrodes: a review [J].
Bi, Zhihong ;
Kong, Qingqiang ;
Cao, Yufang ;
Sun, Guohua ;
Su, Fangyuan ;
Wei, Xianxian ;
Li, Xiaoming ;
Ahmad, Aziz ;
Xie, Lijing ;
Chen, Cheng-Meng .
JOURNAL OF MATERIALS CHEMISTRY A, 2019, 7 (27) :16028-16045
[3]   Graphitized hierarchical porous carbon nanospheres: simultaneous activation/graphitization and superior supercapacitance performance [J].
Chang, Binbin ;
Guo, Yanzhen ;
Li, Yanchun ;
Yin, Hang ;
Zhang, Shouren ;
Yang, Baocheng ;
Dong, Xiaoping .
JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (18) :9565-9577
[4]   Preparation and enhanced supercapacitance performance of porous carbon spheres with a high degree of graphitization [J].
Chang, Binbin ;
Yang, Baocheng ;
Guo, Yanzhen ;
Wang, Yiliang ;
Dong, Xiaoping .
RSC ADVANCES, 2015, 5 (03) :2088-2095
[5]   Natural Plant Template-Derived Cellular Framework Porous Carbon as a High-Rate and Long-Life Electrode Material for Energy Storage [J].
Chen, Xun ;
Chi, Manzhou ;
Xing, Linlin ;
Xie, Xuan ;
Liu, Simin ;
Liang, Yeru ;
Zheng, Mingtao ;
Hu, Hang ;
Dong, Hanwu ;
Liu, Yingliang ;
Jiang, San Ping ;
Xiao, Yong .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2019, 7 (06) :5845-5855
[6]   Untangling the respective effects of heteroatom-doped carbon materials in batteries, supercapacitors and the ORR to design high performance materials [J].
Feng, Xin ;
Bai, Ying ;
Liu, Mingquan ;
Li, Ying ;
Yang, Haoyi ;
Wang, Xinran ;
Wu, Chuan .
ENERGY & ENVIRONMENTAL SCIENCE, 2021, 14 (04) :2036-2089
[7]   Activated carbon from lignocellulosics precursors: A review of the synthesis methods, characterization techniques and applications [J].
Gonzalez-Garcia, P. .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2018, 82 :1393-1414
[8]   Effect of activation time on the properties of activated carbons prepared by microwave-assisted activation for electric double layer capacitors [J].
He, Xiaojun ;
Geng, Yejing ;
Qiu, Jieshan ;
Zheng, Mingdong ;
Long, Suan ;
Zhang, Xiaoyong .
CARBON, 2010, 48 (05) :1662-1669
[9]   Biomass waste-derived porous graphitic carbon for high-performance supercapacitors [J].
Hegde, Shreeganesh Subraya ;
Bhat, Badekai Ramachandra .
JOURNAL OF ENERGY STORAGE, 2024, 76
[10]  
Hegde SS., 2023, Sustainable Materials for Electrochemical Capacitors, P19