C1 functionalization of imidazo heterocycles via carbon dioxide fixation

被引：5

作者：

Fragkiadakis, Michael ^{[1
]}

Anastasiou, Paraskevi-Kleio ^{[1
]}

Volyrakis, Ioannis ^{[1
]}

Pantousas, Apostolos ^{[2
]}

Stoumpos, Constantinos C. ^{[2
]}

Neochoritis, Constantinos G. ^{[1
]}

机构：

[1] Univ Crete, Dept Chem, Iraklion 70013, Greece

[2] Univ Crete, Dept Mat Sci & Technol, Iraklion 70013, Greece

来源：

CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 97期

关键词：

ONE-POT SYNTHESIS; CO2; OXAZOLIDINONES; 2-OXAZOLIDINONES; TRANSFORMATION; ALKYLATION; INHIBITORS; CONVERSION; PYRAZINES; CASCADE;

D O I：

10.1039/d3cc04597h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Utilizing CO2 as a one-carbon building block in the preparation of high-value chemical entities is a cornerstone of modern organic synthesis. Herein, we exemplify this strategy through a mild, one-pot methodology that gives rapid access to N-heteroaryl substituted 6-, 8- and 9-membered carbamates via CO2 fixation.

引用

收藏

页码：14411 / 14414

页数：4

相关论文

共 50 条

[21] Carbon Dioxide Hydrogenation to C1 Chemicals for E-Fuel Synthesis: A Comparative Thermodynamic Analysis Considering Solid Carbon Formation [J].

Sahebdelfar, Saeed ;

Bijani, Parisa Moghimpour .

WASTE AND BIOMASS VALORIZATION, 2025,

[22] Base metal catalyzed (De)hydrogenative formylation and methylation reactions utilizing carbon dioxide and methanol as C1 sources [J].

Jalwal, Sachin ;

Atreya, Vaishnavi ;

Singh, Tushar ;

Chakraborty, Subrata .

TETRAHEDRON LETTERS, 2021, 82

[23] Carbon dioxide fixation via production of succinic acid from glycerol in engineered Saccharomyces cerevisiae [J].

Malubhoy, Zahabiya ;

Bahia, Frederico Mendonca ;

de Valk, Sophie Claire ;

de Hulster, Erik ;

Rendulic, Toni ;

Ortiz, Juan Paulo Ragas ;

Xiberras, Joeline ;

Klein, Mathias ;

Mans, Robert ;

Nevoigt, Elke .

MICROBIAL CELL FACTORIES, 2022, 21 (01)

[24] A new mechanism for the selectivity to C1 and C2 species in the electrochemical reduction of carbon dioxide on copper electrodes [J].

Schouten, K. J. P. ;

Kwon, Y. ;

van der Ham, C. J. M. ;

Qin, Z. ;

Koper, M. T. M. .

CHEMICAL SCIENCE, 2011, 2 (10) :1902-1909

[25] Three-Component Synthesis of Oxazolidinones via Phosphine-Catalyzed Fixation of Carbon Dioxide and Mechanistic Investigation in Mass Spectrometry [J].

Li, Wangyu ;

Zhou, Shiwen ;

Tang, He ;

Chu, Fengjian ;

Feng, Hongru ;

Pan, Yuanjiang .

JOURNAL OF ORGANIC CHEMISTRY, 2025, 90 (14) :4888-4896

[26] Advancements in six-membered cyclic carbonate (1,3-dioxan-2-one) synthesis utilizing carbon dioxide as a C1 source [J].

Hosseinian, Akram ;

Farshbaf, Sepideh ;

Mohammadi, Robab ;

Monfared, Aazam ;

Vessally, Esmail .

RSC ADVANCES, 2018, 8 (32) :17976-17988

[27] Mechanism of transition-metal-cluster-anchored g-C3N4 for the electrochemical catalytic hydrogenation of carbon dioxide to C1 products [J].

Zhang, Shuwei ;

Feng, Huining ;

Tang, Ruiyang ;

Li, Hui ;

Wu, Yang .

COMPUTATIONAL AND THEORETICAL CHEMISTRY, 2025, 1244

[28] Metal Nanoparticles: An Efficient Tool for Heterocycles Synthesis and Their Functionalization via C-H Activation [J].

Saha, Debasree ;

Mukhopadhyay, Chhanda .

CURRENT ORGANOCATALYSIS, 2019, 6 (02) :79-91

[29] Boosting carbon dioxide electroreduction to C1 feedstocks via theory-guided tailoring oxygen defects in porous tin-oxide nanocubes [J].

He, Haichuan ;

Liu, Kang ;

Liang, Kaixin ;

Mustapha, Abdulhadi ;

Wang, Zheng ;

Wu, Linlin ;

Yang, Congcheng ;

Deng, Liu ;

Guo, Shaojun ;

Liu, You-Nian .

JOURNAL OF CATALYSIS, 2020, 385 :246-254

[30] Ligand Functionalization in Zirconium-Based Metal-Organic Frameworks for Enhanced Carbon Dioxide Fixation [J].

Sun, Xiaodong ;

Shi, Litong ;

Hu, Haijun ;

Huang, Hongwei ;

Ma, Tianyi .

ADVANCED SUSTAINABLE SYSTEMS, 2020, 4 (09)

← 1 2 3 4 5 →