Visible light-embedded CuO/ZnO twofold execution for photocatalysis and photoluminescence

被引:3
作者
Elgorban, Abdallah M. M. [1 ]
Sivaganesh, D. [2 ]
Arunpandian, Muthuraj [3 ]
Bahkali, Ali H. H. [1 ]
Eswaramoorthy, Rajalakshmanan [4 ]
Zaghloul, Nouf S. S. [5 ]
Verma, Meenakshi [6 ]
Syed, Asad [1 ]
机构
[1] King Saud Univ, Coll Sci, Dept Bot & Microbiol, PO 2455, Riyadh 11451, Saudi Arabia
[2] Kalasalingam Acad Res & Educ, Int Res Ctr, Dept Phys, Virudunagar 626126, Tamil Nadu, India
[3] PSR Engn Coll, Dept Chem, Sivakasi 626140, Tamil Nadu, India
[4] Saveetha Inst Med & Tech Sci SIMATS, Saveetha Dent Coll & Hosp, Dept Prosthodont, Chennai 600077, India
[5] Univ Bristol, Bristol Ctr Funct Nanomat, HH Wills Phys Lab, Tyndall Ave, Bristol BS8 1FD, Avon, England
[6] Chandigarh Univ, Univ Ctr Res & Dev, Dept Chem, Mohali, India
关键词
Photodegradation; ZnO@CuO; Organic pollutants; Rietveld refinement analysis; Photoluminescence; ZNO; OXIDE; NANOMATERIALS; NANOSTRUCTURES;
D O I
10.1007/s10832-023-00311-3
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In the present work, tackle the two issues with one single activity resource that strategy has followed. The organic dye methyl orange (MO) and drug ciprofloxacin (CIP) have been effectively degraded by the synthesized ZnO@CuO under visible light irradiation. The hexagonal structured zinc oxide (ZnO), monoclinic structured copper oxide (CuO) and the mixed phase of ZnO@CuO has been prepared by the hydrothermal method. The structural characterization of prepared materials has been analyzed by powder X-ray diffraction (P-XRD) and the Rietveld refinement technique. The surface morphology of synthesized materials has been measured by scanning electron microscope characterization. The luminescence performance of prepared materials has studied by photoluminescence (PL) characterization. The photocatalytic results suggest that the ZnO@CuO composite is the effective candidate of degradation of ciprofloxacin antibiotic drug and methyl orange dye. From the results, ZnO@CuO revealed excellent photocatalytic behavior for CIP and MO degradation under stimulated sun light irradiation with the efficiency of above 95%. In addition, the optimum parameters were analyzed to the degradation process. This type of affordable photocatalyst gives a new beginning for further research studies. In addition, the electron density distribution analysis of synthesized materials has been studied.
引用
收藏
页码:12 / 27
页数:16
相关论文
共 50 条
  • [31] Phenol and Cr(VI) degradation with Mn ion doped ZnO under visible light photocatalysis
    Kumar, K. V. Ashok
    Amanchi, Srinivasa Rao
    Sreedhar, B.
    Ghosal, P.
    Subrahmanyam, Ch.
    RSC ADVANCES, 2017, 7 (68): : 43030 - 43039
  • [32] Carbon-doped ZnO nanostructures synthesized using vitamin C for visible light photocatalysis
    Cho, Seungho
    Jang, Ji-Wook
    Lee, Jae Sung
    Lee, Kun-Hong
    CRYSTENGCOMM, 2010, 12 (11): : 3929 - 3935
  • [33] Visible light active photocatalysis on block copolymer induced strings of ZnO nanoparticles doped with carbon
    Kochuveedu, Saji Thomas
    Jang, Yoon Hee
    Jang, Yu Jin
    Kim, Dong Ha
    JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (03) : 898 - 905
  • [34] Controlling oxygen vacancies and enhanced visible light photocatalysis of CeO2/ZnO nanocomposites
    Zhang, Qian
    Zhao, Xiaoru
    Duan, Libing
    Shen, Hao
    Liu, Ruidi
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2020, 392
  • [35] Rational fabrication of plasmonic responsive N-Ag-TiO2-ZnO nanocages for photocatalysis under visible light
    Qin, Guohui
    Sun, Xinxin
    Xiao, Yaoyao
    Liu, Fusheng
    JOURNAL OF ALLOYS AND COMPOUNDS, 2019, 772 : 885 - 899
  • [36] Role of surface defects on visible light enabled plasmonic photocatalysis in Au-ZnO nanocatalysts
    Bora, T.
    Myint, M. T. Z.
    Al-Harthi, S. H.
    Dutta, J.
    RSC ADVANCES, 2015, 5 (117) : 96670 - 96680
  • [37] Removal and regrowth inhibition of microalgae using visible light photocatalysis with ZnO nanorods: A green technology
    Sathe, Priyanka
    Myint, Myo Tay Zar
    Dobretsov, Sergey
    Dutta, Joydeep
    SEPARATION AND PURIFICATION TECHNOLOGY, 2016, 162 : 61 - 67
  • [38] Facet-selective photodeposition of gold nanoparticles on faceted ZnO crystals for visible light photocatalysis
    Wang, Xuewen
    Wang, Wuyou
    Miao, Yuanquan
    Feng, Gang
    Zhang, Rongbin
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2016, 475 : 112 - 118
  • [39] Visible-light-induced photocatalytic performances of ZnO-CuO nanocomposites for degradation of 2,4-dichlorophenol
    Sherly, E. D.
    Vijaya, J. Judith
    Kennedy, L. John
    CHINESE JOURNAL OF CATALYSIS, 2015, 36 (08) : 1263 - 1272
  • [40] Visible light induced α-amino acid synthesis from carbon dioxide using nanostructured ZnO/CuO heterojunction photocatalyst
    Saini, Sandhya
    Prabhu, Yendrapati Taraka
    Sreedhar, B.
    Prajapati, Pankaj Kumar
    Pal, Ujjwal
    Jain, Suman L.
    MATERIALIA, 2020, 12