Visible light-embedded CuO/ZnO twofold execution for photocatalysis and photoluminescence

被引:3
作者
Elgorban, Abdallah M. M. [1 ]
Sivaganesh, D. [2 ]
Arunpandian, Muthuraj [3 ]
Bahkali, Ali H. H. [1 ]
Eswaramoorthy, Rajalakshmanan [4 ]
Zaghloul, Nouf S. S. [5 ]
Verma, Meenakshi [6 ]
Syed, Asad [1 ]
机构
[1] King Saud Univ, Coll Sci, Dept Bot & Microbiol, PO 2455, Riyadh 11451, Saudi Arabia
[2] Kalasalingam Acad Res & Educ, Int Res Ctr, Dept Phys, Virudunagar 626126, Tamil Nadu, India
[3] PSR Engn Coll, Dept Chem, Sivakasi 626140, Tamil Nadu, India
[4] Saveetha Inst Med & Tech Sci SIMATS, Saveetha Dent Coll & Hosp, Dept Prosthodont, Chennai 600077, India
[5] Univ Bristol, Bristol Ctr Funct Nanomat, HH Wills Phys Lab, Tyndall Ave, Bristol BS8 1FD, Avon, England
[6] Chandigarh Univ, Univ Ctr Res & Dev, Dept Chem, Mohali, India
关键词
Photodegradation; ZnO@CuO; Organic pollutants; Rietveld refinement analysis; Photoluminescence; ZNO; OXIDE; NANOMATERIALS; NANOSTRUCTURES;
D O I
10.1007/s10832-023-00311-3
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In the present work, tackle the two issues with one single activity resource that strategy has followed. The organic dye methyl orange (MO) and drug ciprofloxacin (CIP) have been effectively degraded by the synthesized ZnO@CuO under visible light irradiation. The hexagonal structured zinc oxide (ZnO), monoclinic structured copper oxide (CuO) and the mixed phase of ZnO@CuO has been prepared by the hydrothermal method. The structural characterization of prepared materials has been analyzed by powder X-ray diffraction (P-XRD) and the Rietveld refinement technique. The surface morphology of synthesized materials has been measured by scanning electron microscope characterization. The luminescence performance of prepared materials has studied by photoluminescence (PL) characterization. The photocatalytic results suggest that the ZnO@CuO composite is the effective candidate of degradation of ciprofloxacin antibiotic drug and methyl orange dye. From the results, ZnO@CuO revealed excellent photocatalytic behavior for CIP and MO degradation under stimulated sun light irradiation with the efficiency of above 95%. In addition, the optimum parameters were analyzed to the degradation process. This type of affordable photocatalyst gives a new beginning for further research studies. In addition, the electron density distribution analysis of synthesized materials has been studied.
引用
收藏
页码:12 / 27
页数:16
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