High Poisonous Cd Ions Removal by Ru-ZnO-g-C3N4 Nanocomposite: Description and Adsorption Mechanism

被引:13
|
作者
Ismail, Mukhtar [1 ]
Albadri, Abuzar [2 ]
Aissa, Mohamed Ali Ben [1 ]
Modwi, Abueliz [1 ]
Saleh, Sayed M. [2 ,3 ]
机构
[1] Qassim Univ, Coll Sci & Arts, Dept Chem, Ar Rass 51921, Saudi Arabia
[2] Qassim Univ, Coll Sci, Dept Chem, Buraydah 51452, Saudi Arabia
[3] Suez Univ, Fac Petr & Min Engn, Dept Sci & Math, Chem Branch, Suez 43721, Egypt
关键词
Ru-ZnO-g-C3N4; nanocomposite; poisonous Cd ions; removal kinetic; adsorption mechanism; AQUEOUS-SOLUTION; PHOTOCATALYTIC ACTIVITY; PB II; KINETICS; CD(II); PHENOL; G-C3N4; EFFICIENCY; CAPACITY; ISOTHERM;
D O I
10.3390/inorganics11040176
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Ru-ZnO-g-C3N4 nanocomposite was made using a straightforward ultrasonication method and evaluated for its potential to remove Cd ions from aqueous environments. X-ray diffraction analysis confirms composite production with an average crystalline size of 6.61 nm, while transmission electron microscopy results indicate nanosheet-like nanomaterials with uniform elements distribution. Measurements of N2 adsorption-desorption reveal the creation of a mesoporous structure with a BET surface area of approximately 257 m(2)/g. Fourier converted infrared reveals vibrational modes for O-H, amino groups, triazine, and Ru-ZnO. In contrast, X-ray photoelectron spectroscopy investigation reveals the presence of the elements Ru, Zn, O, N, and C. Ru-ZnO-g-C3N4 nanocomposite has remarkable adsorption efficiency for aqueous Cd ions, achieving 475.5 mg/g in 18 min. This study reveals that the Ru-ZnO-g-C3N4 nanocomposite may be used as an effective and reusable adsorbent for removing Cd ions during wastewater treatment and, possibly, for eliminating other toxic metal ions.
引用
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页数:14
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