A green and efficient technology to recover rare earth elements from weathering crusts

被引:98
作者
Wang, Gaofeng [1 ,2 ,3 ,4 ]
Xu, Jie [1 ,2 ,3 ,4 ]
Ran, Lingyu [1 ,2 ,3 ,4 ]
Zhu, Runliang [1 ,2 ,3 ,4 ]
Ling, Bowen [5 ]
Liang, Xiaoliang [1 ,2 ,3 ,4 ]
Kang, Shichang [1 ,2 ,3 ,4 ]
Wang, Yuanyuan [1 ,2 ,3 ,4 ]
Wei, Jingming [1 ,2 ,3 ,4 ]
Ma, Lingya [1 ,2 ,3 ,4 ]
Zhuang, Yanfeng [6 ]
Zhu, Jianxi [1 ,2 ,3 ,4 ]
He, Hongping [1 ,2 ,3 ,4 ]
机构
[1] Chinese Acad Sci, Guangzhou Inst Geochem, CAS Key Lab Mineral & Met, Guangzhou, Peoples R China
[2] Chinese Acad Sci, Guangzhou Inst Geochem, Guangdong Prov Key Lab Mineral Phys & Mat, Guangzhou, Peoples R China
[3] Chinese Acad Sci, Ctr Excellence Deep Earth Sci, Guangzhou, Peoples R China
[4] Univ Chinese Acad Sci, Beijing, Peoples R China
[5] Chinese Acad Sci, Inst Mech, Beijing, Peoples R China
[6] Wuhan Univ, Sch Civil Engn, Wuhan, Peoples R China
基金
国家重点研发计划; 中国国家自然科学基金;
关键词
ELECTROKINETIC REMEDIATION; PULSE CURRENT; ORE; SOIL; COMPOUND; ALUMINUM; EXTRACTION; REMOVAL;
D O I
10.1038/s41893-022-00989-3
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Heavy rare earth elements (HREEs) such as Gd-Lu, Sc and Y are irreplaceable metals for a number of critical (including clean) technologies, but they are scarce. Ion-adsorption deposits, which form within weathering crusts, supply more than 95% of the global HREE demand. However, these deposits are currently mined via ammonium-salt-based leaching techniques that are responsible for severe environmental damage and show low recovery efficiency. As a result, the adoption of such techniques is restricted for REE mining, further exacerbating REE scarcity, which in turn could lead to supply chain disruptions. Here we report the design of an innovative REE mining technique, electrokinetic mining (EKM), which enables green, efficient and selective recovery of REEs from weathering crusts. Its feasibility is demonstrated via bench-scale, scaled-up and on-site field experiments. Compared with conventional techniques, EKM achieves similar to 2.6 times higher recovery efficiency, an similar to 80% decrease in leaching agent usage and a similar to 70% reduction in metallic impurities in the obtained REEs. As an additional benefit, the results point to an autonomous purification mechanism for REE enrichment, wherein the separation process is based on the mobility and reactivity diversity between REEs and metallic impurities. Overall, the evidence presented suggests that EKM is a viable mining technique, revealing new paths for the sustainable harvesting of natural resources.
引用
收藏
页码:81 / +
页数:15
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