Binder-free Three-dimensional (3D) printing of Cellulose-ZIF8 (CelloZIF-8) for water treatment and carbon dioxide (CO2) adsorption

被引:56
作者
Abdelhamid, Hani Nasser [1 ,3 ,4 ]
Sultan, Sahar [1 ,2 ]
Mathew, Aji P. [1 ,2 ]
机构
[1] Stockholm Univ, Div Mat & Environm Chem, Svante Arrhenius Vag 16 C, S-10691 Stockholm, Sweden
[2] Wallenberg Wood Sci Ctr, Teknikringen 56-58, S-10044 Stockholm, Sweden
[3] Assiut Univ, Fac Sci, Dept Chem, Adv Multifunct Mat Lab, Assiut 71515, Egypt
[4] British Univ Egypt BUE, Nanotechnol Res Ctr NTRC, POB 43,Suez Desert Rd, El Shorouk City 11837, Cairo, Egypt
关键词
3D printing; Cellulose-MOFs composite; CelloMOF; Water removal; CO; 2; adsorption; ZEOLITIC IMIDAZOLATE FRAMEWORKS; MOF;
D O I
10.1016/j.cej.2023.143567
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Metal-organic frameworks (MOFs) have advanced several applications, including energy, biomedical and envi-ronmental remediation. However, most of the reported MOF materials are in powder form limiting their ap-plications. This study reported the processing of MOF via three-dimensional (3D) printing of cellulose-MOFs (denoted as CelloMOFs). The 3D printing procedure involved a one-pot method including three steps: gel for-mation, 3D printing, and in-situ growth of MOF crystals. This procedure offered 3D printing of CelloMOF via a binder-free method with high loading of 67.5 wt%. The 3D-printed porous structures were used as adsorbents for carbon dioxide (CO2), dye, and heavy metal ions. They can be also used as catalysts for the degradation of water pollutants such as organic dyes. The materials can be separated easily without requiring extra procedures such as centrifugation or filtration. The materials offered complete (>99%) removal of organic dyes within 10 min with high selectivity toward anionic dyes e.g, methyl blue (MeB). The materials exhibited CO2 and heavy metal ions adsorption capacities of 0.63 mmol/g (27.7 mg/g) and 8-328 mg/g, respectively, with good recyclability. Our methodology will open new venues for advanced 3D printing of CelloMOF and its applications for water treatment and air purification.
引用
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页数:11
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