Improved quantum yield in geometrically constrained tetraphenylethylene-based metalorganic frameworks

被引：2

作者：

Stawiasz, Katherine J. ^{[1
,2
]}

Deneff, Jacob I. ^{[3
]}

Reyes, Raphael A. ^{[3
]}

Woods, Toby J. ^{[6
,7
]}

Rohwer, Lauren E. S. ^{[4
]}

Valdez, Nichole ^{[5
]}

Rodriguez, Mark A. ^{[5
]}

Lawal, Abdul ^{[2
]}

Moore, Jeffrey S. ^{[1
,2
]}

Gallis, Dorina F. Sava ^{[3
]}

机构：

[1] Univ Illinois, Beckman Inst Adv Sci & Technol, Urbana, IL 61801 USA

[2] Univ Illinois, Dept Chem, Urbana, IL 61801 USA

[3] Sandia Natl Labs, Nanoscale Sci Dept, Albuquerque, NM 87185 USA

[4] Sandia Natl Labs, Adv Packaging Integrat Dept, Albuquerque, NM 87185 USA

[5] Sandia Natl Labs, Mat Characterizat & Performance Dept, Albuquerque, NM 87185 USA

[6] Univ Illinois, George L Clark Xray Facil, Urbana, IL 61801 USA

[7] Univ Illinois, 3M Mat Lab, Urbana, IL 61801 USA

来源：

CRYSTENGCOMM | 2023年 / 25卷 / 18期

关键词：

METAL-ORGANIC FRAMEWORKS; DESIGN;

D O I：

10.1039/d3ce00228d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein, we report the synthesis of a novel, tetraphenylethylenebased ligand for metal-organic frameworks (MOFs). Incorporation of this ligand into a Zn- or Eu-based MOF increased the quantum yield (QY) by almost 2.5x compared to the linker alone. Furthermore, the choice of guest solvent impacted the QY and solvatochromatic response. These shifts are consistent with solvent dielectric constant as well as molecular polarizability.

引用

页码：2701 / 2705

页数：5

共 31 条

[1] Autoluminescent Metal-Organic Frameworks (MOFs): Self-Photoemission of a Highly Stable Thorium MOF [J].

Andreo, Jacopo ;

Priola, Emanuele ;

Alberto, Gabriele ;

Benzi, Paola ;

Marabello, Domenica ;

Proserpio, Davide M. ;

Lamberti, Carlo ;

Diana, Eliano .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (43) :14144-14149

[2] Solvatochromic covalent organic frameworks [J].

Ascherl, Laura ;

Evans, Emrys W. ;

Hennemann, Matthias ;

Di Nuzzo, Daniele ;

Hufnagel, Alexander G. ;

Beetz, Michael ;

Friend, Richard H. ;

Clark, Timothy ;

Bein, Thomas ;

Auras, Florian .

NATURE COMMUNICATIONS, 2018, 9

[3] Polarizabilities of solvents from the chemical composition [J].

Bosque, R ;

Sales, J .

JOURNAL OF CHEMICAL INFORMATION AND COMPUTER SCIENCES, 2002, 42 (05) :1154-1163

[4] Unveiling the Mechanism of Water-Triggered Diplex Transformation and Correlating the Changes in Structures and Separation Properties [J].

Cao, Li-Hui ;

Wei, Yong-Sheng ;

Xu, Hong ;

Zang, Shuang-Quan ;

Mak, Thomas C. W. .

ADVANCED FUNCTIONAL MATERIALS, 2015, 25 (41) :6448-6457

[5] A Controllable Gate Effect in Cobalt(II) Organic Frameworks by Reversible Structure Transformations [J].

Chen, Qiang ;

Chang, Ze ;

Song, Wei-Chao ;

Song, Han ;

Song, Hai-Bin ;

Hu, Tong-Liang ;

Bu, Xian-He .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (44) :11550-11553

[6] Luminescent Functional Metal-Organic Frameworks [J].

Cui, Yuanjing ;

Yue, Yanfeng ;

Qian, Guodong ;

Chen, Banglin .

CHEMICAL REVIEWS, 2012, 112 (02) :1126-1162

[7] Industrial applications of metal-organic frameworks [J].

Czaja, Alexander U. ;

Trukhan, Natalia ;

Mueller, Ulrich .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1284-1293

[8] Covert MOF-Based Photoluminescent Tags via Tunable Linker Energetics [J].

Deneff, Jacob, I ;

Rohwer, Lauren E. S. ;

Butler, Kimberly S. ;

Valdez, Nichole R. ;

Rodriguez, Mark A. ;

Luk, Ting S. ;

Sava Gallis, Dorina F. .

ACS APPLIED MATERIALS & INTERFACES, 2022, 14 (02) :3038-3047

[9] Encoding Multilayer Complexity in Anti-Counterfeiting Heterometallic MOF-Based Optical Tags [J].

Deneff, Jacob I. ;

Butler, Kimberly S. ;

Rohwer, Lauren E. S. ;

Pearce, Charles J. ;

Valdez, Nichole R. ;

Rodriguez, Mark A. ;

Luk, Ting S. ;

Sava Gallis, Dorina F. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (03) :1203-1211

[10] Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].

Eddaoudi, M ;

Kim, J ;

Rosi, N ;

Vodak, D ;

Wachter, J ;

O'Keeffe, M ;

Yaghi, OM .

SCIENCE, 2002, 295 (5554) :469-472

← 1 2 3 4 →