Photocatalytic and Electrocatalytic Generation of Hydrogen Peroxide: Principles, Catalyst Design and Performance

被引：75
作者：
Guo, Yan [1 ,2 ]
Tong, Xili [1 ]
Yang, Nianjun [3 ,4 ,5 ]
机构：
[1] Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Univ Siegen, Inst Mat Engn, D-57076 Siegen, Germany
[4] Hasselt Univ, Dept Chem, B-3590 Diepenbeek, Belgium
[5] Hasselt Univ, IMO IMOMEC, B-3590 Diepenbeek, Belgium
来源：
NANO-MICRO LETTERS | 2023年 / 15卷 / 01期
关键词：
H2O2; generation; Photocatalysts; Electrocatalysts; Reaction mechanisms; GRAPHITIC CARBON NITRIDE; 2-ELECTRON WATER OXIDATION; NITROGEN-DOPED CARBON; H2O2 PRODUCTION ABILITY; GRAPHENE-QUANTUM-DOTS; METAL-FREE ELECTROCATALYSTS; HIGHLY SELECTIVE PRODUCTION; OXYGEN REDUCTION REACTION; VISIBLE-LIGHT; MOLECULAR-OXYGEN;
D O I：
10.1007/s40820-023-01052-2
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Hydrogen peroxide -(H2O2) is a high-demand organic chemical reagent and has been widely used in various modern industrial applications. Currently, the prominent method for the preparation of -H2O2 is the anthraquinone oxidation. Unfortunately, it is not conducive to economic and sustainable development since it is a complex process and involves unfriendly environment and potential hazards. In this context, numerous approaches have been developed to synthesize -H2O2. Among them, photo/electro-catalytic ones are considered as two of the most promising manners for on- site synthesis of -H2O2. These alternatives are sustainable in that only water or -O-2 is required. Namely, water oxidation (WOR) or oxygen reduction (ORR) reactions can be further coupled with clean and sustainable energy. For photo/electro-catalytic reactions for -H2O2 generation, the design of the catalysts is extremely important and has been extensively conducted with an aim to obtain ultimate catalytic performance. This article overviews the basic principles of WOR and ORR, followed by the summary of recent progresses and achievements on the design and performance of various photo/electro-catalysts for -H2O2 generation. The related mechanisms for these approaches are highlighted from theoretical and experimental aspects. Scientific challenges and opportunities of engineering photo/electro-catalysts for -H2O2 generation are also outlined and discussed.
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页数：49
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