Fabricating multi-porous carbon anode with remarkable initial coulombic efficiency and enhanced rate capability for sodium-ion batteries

Due to the abundant sodium reserves and high safety, sodium ion batteries (SIBs) are foreseen a promising future. While, hard carbon materials are very suitable for the anode of SIBs owing to their structure and cost advantages. However, the unsatisfactory initial coulombic efficiency (ICE) is one of the crucial blemishes of hard carbon materials and the slow sodium storage kinetics also hinders their wide application. Herein, with spherical nano SiO2 as pore-forming agent, gelatin and polytetrafluoroethylene as carbon sources, a multi-porous carbon (MPC) material can be easily obtained via a co-pyrolysis method, by which carbonization and template removal can be achieved synchronously without the assistance of strong acids or strong bases. As a result, the MPC anode exhibited remarkable ICE of 83% and a high rate capability (208 mAh/g at 5 A/g) when used in sodium-ion half cells. Additionally, coupling with Na3V2(PO4)(3) as the cathode to assemble full cells, the as-fabricated MPC//NVP full cell delivered a good rate capability (146 mAh/g at 5 A/g) as well, implying a good application prospect the MPC anode has (c) 2022 Published by Elsevier B.V. on behalf of Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences.