A review on zeolite catalyst for deNOx performance in ammonia-selective catalytic reduction

被引：24
|
作者：
Kumar, M. Sunil [1 ]
Alphin, M. S. [1 ]
Kumar, P. Senthil [2 ,3 ]
Raja, S. [4 ]
机构：
[1] Sri Sivasubramaniya Nadar Coll Engn, Dept Mech Engn, Kalavakkam 603110, Tamil Nadu, India
[2] Sri Sivasubramaniya Nadar Coll Engn, Dept Chem Engn, Kalavakkam 603110, Tamil Nadu, India
[3] Sri Sivasubramaniya Nadar Coll Engn, Ctr Excellence Water Res CEWAR, Kalavakkam 603110, Tamil Nadu, India
[4] Indian Inst Technol, Dept Mech Engn, Madras 600036, India
来源：
FUEL | 2023年 / 334卷
关键词：
Selective catalytic reduction; NOx emission; Zeolite catalyst; Metal substitute; Deactivation mechanism; TEMPERATURE HYDROTHERMAL STABILITY; CU-ZEOLITE; CU-SAPO-34; CATALYST; NOX REDUCTION; EMISSION CHARACTERISTICS; CU/SAPO-34; CATALYSTS; NH3-SCR CATALYSTS; SI/AL RATIO; SCR; CU-SSZ-13;
D O I：
10.1016/j.fuel.2022.126828
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
Internal combustion (IC) engines rely heavily on NOx emissions. Various studies are being conducted to lower NOx emission in order to achieve the BS-VI norms. This review examines a zeolite catalyst using metal sub-stitutes, primarily copper Cu, and iron Fe, and compares it to a commercial vanadium catalyst in terms of deNOx efficiency and deactivation process. Based on the size of pores of zeolite, it has been classified into large size, medium size and small size zeolites. At low temperature, small pore zeolite with Cu substituted has better deNOx efficiency with higher thermal stability with high-temperature reaction conditions. Whereas, Cu-SSZ-13 & Cu-SAPO-34 exhibits wider temperature window and also exhibits good thermal stability even below 350 degrees C. Si/ Al ratio (SAR) plays a vital role in deNOx efficiency.
引用
收藏
页数：9
相关论文
共 50 条
  • [1] A review of comparison between the traditional catalyst and zeolite catalyst for ammonia-selective catalytic reduction of NOx
    Kumar, M. Sunil
    Alphin, M. S.
    Manigandan, S.
    Vignesh, S.
    Vigneshwaran, S.
    Subash, T.
    FUEL, 2023, 344
  • [2] One-step Synthesis, Characterization and Ammonia-selective Catalytic Reduction Performance of Cu-SAPO-34 Catalyst
    Ren, Yumeng
    Chen, Geng
    Lu, Yudong
    Li, Kun
    Li, Zhaoyang
    Zhu, Yingying
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2025, 28 (06)
  • [3] A Bifunctional Multishell Catalyst with a Wide Operating Temperature Window for NOx Abatement by Ammonia-Selective Catalytic Reduction
    Song, Lei
    Shu, Guoqiang
    Ma, Kui
    Liu, Changjun
    Tang, Siyang
    Zhong, Shan
    Yue, Hairong
    Liang, Bin
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2022, 61 (16) : 5410 - 5418
  • [4] Review of the deactivation of selective catalytic reduction DeNOx catalysts
    Jiang, Ye
    Gao, Xiang
    Wu, Weihong
    Zhang, Yongxin
    Zhongguo Dianji Gongcheng Xuebao/Proceedings of the Chinese Society of Electrical Engineering, 2013, 33 (14): : 18 - 31
  • [5] Modelling and parametric investigation of NOx reduction by oxidation precatalyst-assisted ammonia-selective catalytic reduction
    Lung, S-C
    Yoon, W-S
    PROCEEDINGS OF THE INSTITUTION OF MECHANICAL ENGINEERS PART D-JOURNAL OF AUTOMOBILE ENGINEERING, 2009, 223 (D9) : 1193 - 1206
  • [6] Kinetics of ammonia consumption during the selective catalytic reduction of NOx over an iron zeolite catalyst
    Bacher, V.
    Perbandt, C.
    Schwefer, M.
    Siefert, R.
    Pinnow, S.
    Turek, T.
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2015, 162 : 158 - 166
  • [7] Studies on the Preparation and DeNOx Performance of MnxOy/ CNTs Catalyst for Low-temperature Selective Catalytic Reduction
    Ren, Bingnan
    Yang, Qiaowen
    ADVANCES IN APPLIED SCIENCE AND INDUSTRIAL TECHNOLOGY, PTS 1 AND 2, 2013, 798-799 : 231 - +
  • [8] One-pot synthesis, characterization and ammonia-selective catalytic reduction performance of MnSAPO-18 molecular sieves
    Zhou, Chunhuo
    Tu, Xiang
    Jia, Xuehui
    Zhong, Zhiyong
    Ni, Guorong
    Zhao, Zunkang
    Li, Jingxian
    Huang, Hong
    Zou, Changwei
    Huang, Bichun
    Yu, Chenglong
    JOURNAL OF CLEANER PRODUCTION, 2022, 336
  • [9] Selective catalytic reduction of NO by ammonia with fly ash catalyst
    Xuan, XP
    Yue, CT
    Li, SY
    Yao, Q
    FUEL, 2003, 82 (05) : 575 - 579
  • [10] Hydrogen Lean-DeNOx as an Alternative to the Ammonia and Hydrocarbon Selective Catalytic Reduction (SCR)
    Savva, Petros G.
    Costa, Costas N.
    CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 2011, 53 (02): : 91 - 151
12345