Synthesis of Calcium Phosphates with Various Ca/P Ratios Using Phytic Acid as a Green Phosphorus Source

被引：1

作者：

Maeda, Kazuki ^{[1
]}

Aoto, Yoshiki ^{[1
]}

Dohshi, Satoru ^{[1
]}

机构：

[1] Osaka Res Inst Ind Sci & Technol, Izumi, 5941157, Japan

来源：

ACS AGRICULTURAL SCIENCE & TECHNOLOGY | 2023年 / 3卷 / 12期

关键词：

biomass; phytic acid; calcium phosphate; hydroxyapatite; tricalcium phosphate; calciumpyrophosphate; HYDROXYAPATITE; BONE; PHYTATE; NANOPARTICLES;

D O I：

10.1021/acsagscitech.3c00312

中图分类号：

S [农业科学];

学科分类号：

09 ;

摘要：

The synthesis of calcium phosphate from natural phosphorus sources has attracted attention because it saves finite resources. Herein, a novel approach for the synthesis of calcium phosphates using phytic acid as a natural phosphorus source was developed. Calcium phytate was synthesized from phytic acid and calcium chloride, which was mixed with calcium chloride to adjust the Ca/P ratio in the range of 1.0-1.67. The calcination at a temperature of 1100 degree celsius of the mixtures yielded various calcium phosphates, including beta-calcium pyrophosphate, beta-tricalcium phosphates (beta-TCP), and hydroxyapatite (HAP), depending on the Ca/P ratio in the mixtures. Additionally, the X-Ray diffraction (XRD) analysis revealed that alpha-calcium pyrophosphate, spodiosite, and chlorapatite (ClAP) are formed as intermediates during the calcination process.

引用

页码：1148 / 1153

页数：6

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