The effect of LiF on preparation of transparent Eu:La2Zr2O7 ceramics by SPS

被引:1
作者
Necina, Vojtech [1 ]
Mrazek, Jan [2 ]
Pabst, Will [1 ]
Skala, Roman [3 ]
Mikysek, Petr [3 ]
机构
[1] Univ Chem & Technol, Dept Glass & Ceram, Tech 5, Prague 6, Czech Republic
[2] Czech Acad Sci, Inst Photon & Elect, Chaberska 1014-57, Prague 8, Czech Republic
[3] Czech Acad Sci, Inst Geol, Rozvojova 269, Prague 6, Czech Republic
关键词
Transparent ceramics; Sintering additives; Pyrochlore; SINTERING RESISTANCE; OPTICAL-PROPERTIES; FABRICATION; LA2ZR2O7; LUMINESCENCE; MGAL2O4;
D O I
10.1016/j.ceramint.2023.09.364
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Pyrochlores are known for their sintering resistance, therefore, a novel approach for preparation of transparent Eu:La2Zr2O7 pyrochlore ceramics by spark plasma sintering (SPS) is demonstrated with LiF as a sintering ad-ditive. It is shown that LiF not only decreases the on-set temperature and final sintering temperature, but also effectively reduces porosity to achieve transparency. Moreover, since LiF acts only as a transition liquid phase, it does not alter the phase composition even after annealing.
引用
收藏
页码:41007 / 41009
页数:3
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