An aliphatic MOF with a molecular sieving effect for efficient C2H2/C2H4 separation

被引:4
|
作者
Li, Xianzhen [1 ]
Cao, Chen [1 ]
Fan, Ziwen [1 ]
Liu, Jianfa [1 ]
Pham, Tony [2 ]
Forrest, Katherine A. [2 ]
Niu, Zheng [1 ]
机构
[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China
[2] Univ S Florida, Dept Chem, 4202 East Fowler Ave,CHE 205A, Tampa, FL 33620 USA
基金
中国国家自然科学基金;
关键词
METAL-ORGANIC FRAMEWORKS; ETHYLENE; HYDROCARBONS; PURIFICATION; ADSORPTION; ACETYLENE; ETHANE;
D O I
10.1039/d3dt01419c
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A metal-organic framework, SDMOF-1, with rigid pores of about 3.4 & ANGS;, which is appropriate for accommodating C2H2 molecules, exhibits high C2H2 adsorption capacity and great separation capability of the C2H2/C2H4 mixture. This work provides a new method to design aliphatic MOFs with a molecular sieving effect to realize efficient gas separation.
引用
收藏
页码:15338 / 15342
页数:5
相关论文
共 50 条
  • [21] Fluorocarboxylic Acid-Modified MOF-808 with Enhanced Acetylene Adsorption Capacity and C2H2/C2H4 Separation Performance
    Chen, Mohan
    Wang, Yichao
    Fan, Ziwen
    Wang, Yue
    Niu, Zheng
    Lang, Jianping
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2025, 28 (03)
  • [22] Probing Cluster-π Interactions between Cun- and C2H2/C2H4 for Gas Separation
    Yin, Baoqi
    Geng, Lijun
    Zhang, Hanyu
    Jia, Yuhan
    Luo, Zhixun
    JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY, 2021, 32 (09) : 2391 - 2398
  • [23] Microcalorimetric studies of H2, C2H4, and C2H2 adsorption on Pt powder
    Spiewak, BE
    Cortright, RD
    Dumesic, JA
    JOURNAL OF CATALYSIS, 1998, 176 (02) : 405 - 414
  • [24] Highly efficient separation of C2H2 from CO2 and C2H4 enabled by an anion-pillared metalloporphyrin MOF with sandwich-like binding sites
    Liu, Miaoyu
    Gu, Xiao-Wen
    Lin, Chenyan
    Dong, Baixue
    He, Zhongjie
    Xie, Bo
    Zhang, Xu
    Li, Bin
    Wen, Hui-Min
    Hu, Jun
    JOURNAL OF MATERIALS CHEMISTRY A, 2025, 13 (02) : 1034 - 1041
  • [25] Efficient capture of C2H2 from CO2 and CnH4 by a novel fluorinated anion pillared MOF with flexible molecular sieving effect
    Wang, Lingyao
    Xu, Nuo
    Hu, Yongqi
    Sun, Wanqi
    Krishna, Rajamani
    Li, Jiahao
    Jiang, Yunjia
    Duttwyler, Simon
    Zhang, Yuanbin
    NANO RESEARCH, 2023, 16 (02) : 3536 - 3541
  • [26] Design and screening of ionic liquids for C2H2/C2H4 separation by COSMO-RS and experiments
    Zhao, Xu
    Yang, Qiwei
    Xu, Dan
    Bao, Zongbi
    Zhang, Yi
    Su, Baogen
    Ren, Qilong
    Xing, Huabin
    AICHE JOURNAL, 2015, 61 (06) : 2016 - 2027
  • [27] A robust Th-azole framework for highly efficient purification of C2H4 from a C2H4/C2H2/C2H6 mixture
    Xu, Zhenzhen
    Xiong, Xiaohong
    Xiong, Jianbo
    Krishna, Rajamani
    Li, Libo
    Fan, Yaling
    Luo, Feng
    Chen, Banglin
    NATURE COMMUNICATIONS, 2020, 11 (01)
  • [28] A Dy6-cluster-based fcu-MOF with efficient separation of C2H2/C2H4 and selective adsorption of benzene
    Li, Yong-Zhi
    Wang, Hai-Hua
    Wang, Gang-Ding
    Hou, Lei
    Wang, Yao-Yu
    Zhu, Zhonghua
    INORGANIC CHEMISTRY FRONTIERS, 2021, 8 (02) : 376 - 382
  • [29] Simultaneous Trapping of C2H2 and C2H6 from a Ternary Mixture of C2H2/C2H4/C2H6 in a Robust Metal-Organic Framework for the Purification of C2H4
    Hao, Hong-Guo
    Zhao, Yun-Feng
    Chen, Di-Ming
    Yu, Jia-Mei
    Tan, Kui
    Ma, Shengqian
    Chabal, Yves
    Zhang, Zhi-Ming
    Dou, Jian-Min
    Xiao, Zi-Hui
    Day, Gregory
    Zhou, Hong-Cai
    Lu, Tong-Bu
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (49) : 16067 - 16071
  • [30] Impact of partial interpenetration in a hybrid ultramicroporous material on C2H2/C2H4 separation performance
    O'Nolan, Daniel
    Madden, David G.
    Kumar, Amrit
    Chen, Kai-Jie
    Pham, Tony
    Forrest, Katherine A.
    Patyk-Kazmierczak, Ewa
    Yang, Qing-Yuan
    Murray, Claire A.
    Tang, Chiu C.
    Space, Brian
    Zaworotko, Michael J.
    CHEMICAL COMMUNICATIONS, 2018, 54 (28) : 3488 - 3491