Rh(II)-Catalyzed Denitrogenative Reaction of N-Sulfonyl-1,2,3-triazoles with Quinolones and Isoquinolones

被引：1
|
作者：
Pandey, Shivam [1 ]
Parveen, Sabiha [1 ]
Volla, Chandra M. R. [1 ]
机构：
[1] Indian Inst Technol Bombay Powai, Dept Chem, Mumbai 400076, India
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2023年 / 18卷 / 20期
关键词：
triazoles; Rh-azavinyl carbenes; quinolone; aminoquinoline; aminoisoquinoline; RHODIUM-CATALYZED REACTION; ONE-POT SYNTHESIS; TERMINAL ALKYNES; RHODIUM(II)-CATALYZED ANNULATION; DIASTEREOSELECTIVE SYNTHESIS; FACILE SYNTHESIS; SULFONYL AZIDES; TRANSANNULATION; 1,2,3-TRIAZOLES; PYRROLES;
D O I：
10.1002/asia.202300614
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Herein, we developed an efficient approach to access biologically relevant 2-aminoquinolines and 1-aminoisoquinolines from readily available N-sulfonyl-1,2,3-triazoles and 2-quinolones or 1-isoquinolones. This transformation involves the selective O-H insertion of these derivatives onto the in situ generated Rh-azavinyl carbenes (Rh-AVC) followed by rearrangement. The reaction proceeds smoothly under operationally simple conditions and the protocol was found to be scalable.
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页数：5
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