Green chemistry based benign approach for the synthesis of titanium oxide nanoparticles using extracts of Azadirachta Indica

被引:17
作者
Shekhar, Shashank [1 ]
Singh, Santosh [2 ]
Gandhi, Namita [4 ]
Gautam, Seema [4 ]
Sharma, Bhasha [3 ]
机构
[1] Netaji Subhas Univ Technol, Dwarka Sec 3, New Delhi, India
[2] CSIR Natl Phys Lab, KS Krishnan Marg, New Delhi, India
[3] Univ Delhi, Shivaji Coll, Dept Chem, Delhi, India
[4] Univ Delhi, Deshbandhu Coll, Dept Chem, Delhi, India
来源
CLEANER ENGINEERING AND TECHNOLOGY | 2023年 / 13卷
关键词
Neem extracts; Titanium iso-propoxide; Green chemistry; Biogenic synthesis; TiO2; TIO2; NANOPARTICLES; METALLIC NANOPARTICLES; NEEM LEAVES;
D O I
10.1016/j.clet.2023.100607
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The colossal significance of nanostructured materials and their implications is a coherent incentive for the exploration of novel conventional techniques. This brings attention to the major problem in developing nano-materials i.e. the hazardous nature of reactants used. The hazardous reactants are harmful to the environment. So here, biogenic synthesis of nanostructured materials utilizing natural herb extracts has enthralled prodigious implications owing to its rapid, clean, eco-friendly, non-toxic, cost-effective, and as a flipside pathway to several chemical and physiochemical approaches. Titanium oxide materials have been the cynosure for several propi-tious implications due to their low cost, availability, chemical stability, and biocompatibility. Herein, we developed an efficient green chemistry method for the synthesis of titanium oxide nanoparticles utilizing neem (Azadirachta Indica) extracts. The X-ray diffraction studies revealed the polycrystalline titanium oxide (rutile) structure. The spherical shape of the nanoparticles was observed in TEM and SEM images and their size ranged from 10 to 20 nm. UV-vis studies showed an exciton emission peak at about 380 nm while the IR transmission spectrum revealed the characteristic stretching modes of TiO2. It is envisioned that this novel route for the synthesis of TiO2 nanoparticles could be more beneficial in comparison to other conventional approaches. As the greener approach is being carried out in this paper, therefore, the toxic byproduct is not being released.
引用
收藏
页数:4
相关论文
共 24 条
[1]   Biogenic synthesis of metallic nanoparticles and prospects toward green chemistry [J].
Adil, Syed Farooq ;
Assal, Mohamed E. ;
Khan, Mujeeb ;
Al-Warthan, Abdulrahman ;
Siddiqui, Mohammed Rafiq H. ;
Liz-Marzan, Luis M. .
DALTON TRANSACTIONS, 2015, 44 (21) :9709-9717
[2]   One-step green synthesis of palladium nanoparticles using neem gum (Azadirachta Indica): characterization, reduction of Rhodamine 6G dye and free radical scavenging activity [J].
Amrutham, Santoshikumari ;
Maragoni, Venkatesham ;
Guttena, Veerabhadram .
APPLIED NANOSCIENCE, 2020, 10 (12) :4505-4511
[3]   In-situ green synthesis of nitrogen-doped carbon dots for bioimaging and TiO2 nanoparticles@nitrogen-doped carbon composite for photocatalytic degradation of organic pollutants [J].
Atchudan, Raji ;
Edison, Thomas Nesakumar Jebakumar Immanuel ;
Perumal, Suguna ;
Vinodh, Rajangam ;
Lee, Yong Rok .
JOURNAL OF ALLOYS AND COMPOUNDS, 2018, 766 :12-24
[4]   Green synthesis characterization and antimicrobial activity against Staphylococcus aureus of silver nanoparticles using extracts of neem, onion and tomato [J].
Chand, Kishore ;
Abro, M. Ishaque ;
Aftab, Umair ;
Shah, Ahmer Hussain ;
Lakhan, Muhammad Nazim ;
Cao, Dianxue ;
Mehdi, Ghazanfar ;
Mohamed, Abdalla Mohamed Ali .
RSC ADVANCES, 2019, 9 (30) :17002-17015
[5]   Green approach synthesis of Pd@TiO2 nanoparticles: characterization, visible light active picric acid degradation and anticancer activity [J].
Hariharan, D. ;
Thangamuniyandi, P. ;
Selvakumar, P. ;
Devan, U. ;
Pugazhendhi, A. ;
Vasantharaja, R. ;
Nehru, L. C. .
PROCESS BIOCHEMISTRY, 2019, 87 :83-88
[6]   Green synthesis of metal nanoparticles using plants [J].
Iravani, Siavash .
GREEN CHEMISTRY, 2011, 13 (10) :2638-2650
[7]   A review and recent advances in solar-to-hydrogen energy conversion based on photocatalytic water splitting over doped-TiO2 nanoparticles [J].
Ismael, Mohammed .
SOLAR ENERGY, 2020, 211 :522-546
[8]   Green fabrication of chitosan/tragacanth gum bionanocomposite films having TiO2@Ag hybrid for bioactivity and antibacterial applications [J].
Mallakpour, Shadpour ;
Ramezanzade, Vahid .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2020, 162 (512-522) :512-522
[9]   SYNTHESIS AND CHARACTERIZATION OF MgONANOPARTICLES BY NEEM LEAVES THROUGH GREEN METHOD [J].
Moorthy, S. Krishna ;
Ashok, C. H. ;
Rao, K. Venkateswara ;
Viswanathan, C. .
MATERIALS TODAY-PROCEEDINGS, 2015, 2 (09) :4360-4368
[10]   Green synthesis of mesoporous anatase TiO2 nanoparticles and their photocatalytic activities [J].
Muniandy, Sunderishwary S. ;
Kaus, Noor Haida Mohd ;
Jiang, Zhong-Tao ;
Altarawneh, Mohammednoor ;
Lee, Hooi Ling .
RSC ADVANCES, 2017, 7 (76) :48083-48094