Heterogeneous Metallaphotocatalytic C(sp2)-C(sp3) Cross-Coupling Reactions with Integrated Bipyridyl-Ni(II)-Carbon Nitride

被引：10
|
作者：
Dan, Xiao [1 ]
Yang, Qian [1 ]
Xing, Liuzhuang [1 ]
Tang, Yurong [1 ]
Wang, Wentao [2 ]
Cai, Yunfei [1 ,2 ]
机构：
[1] Chongqing Univ, Sch Chem & Chem Engn, Chongqing Key Lab Theoret & Computat Chem, Chongqing 400044, Peoples R China
[2] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
来源：
ORGANIC LETTERS | 2023年 / 25卷 / 22期
基金：
中国国家自然科学基金;
关键词：
GRAPHITIC CARBON NITRIDE; PHOTOREDOX; PHOTOCATALYST; CATALYSIS;
D O I：
10.1021/acs.orglett.3c01384
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A fullyheterogeneous metallaphotocatalytic C-Ccross-couplingof aryl/vinyl halides with alkyl/allyltrifluoroborates has been developedby employing integrated bipyridyl-Ni-(II)-carbon nitride as a stableand recyclable bifunctional catalyst. This visible-light-mediatedheterogeneous protocol allows for the sustainable synthesis of diversevaluable diarylmethanes and allylarenes in high efficiency.
引用
收藏
页码：4124 / 4129
页数：6
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