Ni-Mo2C hollow carbon nanospheres with enhanced performance as the cathode for lithium sulfur batteries

被引：12

作者：

Bao, Xinlong ^{[1
]}

Li, Yuemin ^{[1
]}

Sun, Lianshan ^{[1
]}

Zhao, Jianxun ^{[1
]}

Chen, Peng ^{[1
]}

Liu, Heng ^{[1
]}

Wang, Xinwei ^{[1
]}

Liu, Wanqiang ^{[1
]}

机构：

[1] Changchun Univ Sci & Technol, Engn Res Ctr Optoelect Funct Mat, Sch Mat Sci & Engn, Minist Educ, Changchun 130022, Peoples R China

来源：

ELECTROCHIMICA ACTA | 2023年 / 441卷

关键词：

Li -S battery; Composite; Hollow carbon sphere; Ni-Mo2C; GRAPHENE; PROGRESS;

D O I：

10.1016/j.electacta.2023.141846

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

How to design the components of the cathode carrier is very important for the adsorption and catalysis of polysulfide conversion. Herein, Ni-Mo2C codoped hollow carbon nanospheres were prepared by two-step solvent synthesis and subsequent heat treatment. Ni as a supplementary material, it can effectively solve the problems of few electrochemical active sites and poor catalytic effect of lithium polysulfide (LPS) of Mo2C carbon nanospheres, and the optimal ratio of Ni to Mo2C was explored. Through the comparison of electrochemical tests, the Ni-Mo2C carbon nanospheres of optimal proportion shows high discharge specific capacity (0.2 C, 1101.3 mAh center dot g - 1) and excellent rate performance (2 C, 692.9 mAh center dot g - 1), which shows the best catalytic and adsorption effect on LPS. In addition, the optimal proportion of Ni-Mo2C carbon nanospheres has the highest lithium ion diffusion coefficient, which can accelerate the transport of Li+ and the kinetics of electrochemical reaction.

引用

页数：8

共 38 条

[1] Facile Fabrication of N-Doped TiO2 Nanoparticles/Carbon Composite with Excellent Electrochemical Properties for Lithium Ion Batteries [J].

Cai, Jinyan ;

Chen, Lin ;

Chen, Xiuying .

JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2020, 20 (04) :2452-2459

[2] Ni/SiO2/Graphene-modified separator as a multifunctional polysulfide barrier for advanced lithium-sulfur batteries [J].

Chen, Chao ;

Jiang, Qingbin ;

Xu, Huifang ;

Zhang, Yaping ;

Zhang, Bingkai ;

Zhang, Zhenyu ;

Lin, Zhan ;

Zhang, Shanqing .

NANO ENERGY, 2020, 76

[3] MOFs-derived porous Mo2C-C nano-octahedrons enable high-performance lithium-sulfur batteries [J].

Chen, Guilin ;

Li, Yijuan ;

Zhong, Wentao ;

Zheng, Fenghua ;

Hu, Junhua ;

Ji, Xiaohong ;

Liu, Weizhen ;

Yang, Chenghao ;

Lin, Zhang ;

Liu, Meilin .

ENERGY STORAGE MATERIALS, 2020, 25 :547-554

[4] A one-pot synthesis of hetero-Co9S8-NiS sheets on graphene to boost lithium-sulfur battery performance [J].

Chen, Liang ;

Xie, Xuefang ;

Zhang, Zhian ;

Kong, Xiangzhong ;

Pan, Anqiang ;

Liang, Shuquan .

INORGANIC CHEMISTRY FRONTIERS, 2020, 7 (11) :2160-2167

[5] Metallic and polar Co9S8 inlaid carbon hollow nanopolyhedra as efficient polysulfide mediator for lithium-sulfur batteries [J].

Chen, Tao ;

Ma, Lianbo ;

Cheng, Baorui ;

Chen, Renpeng ;

Hu, Yi ;

Zhu, Guoyin ;

Wang, Yanrong ;

Liang, Jia ;

Tie, Zuoxiu ;

Liu, Jie ;

Jin, Zhong .

NANO ENERGY, 2017, 38 :239-248

[6] Molecule-Doped Nickel Oxide: Verified Charge Transfer and Planar Inverted Mixed Cation Perovskite Solar Cell [J].

Chen, Wei ;

Zhou, Yecheng ;

Wang, Linjing ;

Wu, Yinghui ;

Tu, Bao ;

Yu, Binbin ;

Liu, Fangzhou ;

Tam, Ho-Won ;

Wang, Gan ;

Djurisic, Aleksandra B. ;

Huang, Li ;

He, Zhubing .

ADVANCED MATERIALS, 2018, 30 (20)

[7]

Cheng Y, 2022, NANO RES, V15, P4091, DOI [10.1007/s12274-021-4035-2, 10.1007/s12274-022-4802-8]

[8] Porous Carbon Mat as an Electrochemical Testing Platform for Investigating the Polysulfide Retention of Various Cathode Configurations in Li-S Cells [J].

Chung, Sheng-Heng ;

Singhal, Richa ;

Kalra, Vibha ;

Manthiram, Arumugam .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2015, 6 (12) :2163-2169

[9]

Dong QF, 2011, PROG CHEM, V23, P533

[10] A Revolution in Electrodes: Recent Progress in Rechargeable Lithium-Sulfur Batteries [J].

Fang, Xin ;

Peng, Huisheng .

SMALL, 2015, 11 (13) :1488-1511

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