Reactions of a P-N stabilised aluminium dihydride with ruthenium hydride complexes

被引：0
作者：
Pecharman, Anne-Frederique M. [1 ]
Falconer, Rosalyn L. [2 ,3 ]
Owen, Esme [1 ]
Cowley, Michael J. [2 ]
Lowe, John P. [1 ]
McMullin, Claire L. [1 ]
Mahon, Mary F. [1 ]
Whittlesey, Michael K. [1 ]
机构：
[1] Univ Bath, Dept Chem, Bath BA2 3QD, England
[2] Univ Edinburgh, Sch Chem, Joseph Black Bldg, David Brewster Rd, Edinburgh EH9 3FJ, Scotland
[3] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Z1, Canada
来源：
POLYHEDRON | 2023年 / 243卷
基金：
英国工程与自然科学研究理事会; 欧洲研究理事会;
关键词：
Ruthenium; Aluminium; Hydride; Heterobimetallic; Density functional theory; H BOND ACTIVATION; MOLECULAR-STRUCTURE; COVALENT RADII; METAL; DEHYDROGENATION; ENERGY; APPROXIMATION; HYDROGENATION; COORDINATION; REACTIVITY;
D O I：
10.1016/j.poly.2023.116531
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Treatment of [Ru(L)(PPh3)2(CO)H2] (L = PPh3, IMes; IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) with an N-mesityl amidophosphine aluminium dihydride complex (Al(P-N)H2) gives [Ru(PPh3)2(CO)H3{Al (P-N)H}] (2) and [Ru(IMes)(PPh3)(CO)H3{Al(P-N)H}] (4), which are present in solution as mixtures of diastereomers. Crystal structure determinations and density functional theory (DFT) calculations suggest both 2 and 4 can be formulated as [Ru(L)(PPh3)(CO)H3][Al(P-N)H] complexes with bridging hydride ligands.
引用
收藏
页数：7
相关论文
共 50 条
  • [1] Catalytic Conversion of Ethanol to n-Butanol Using Ruthenium P-N Ligand Complexes
    Wingad, Richard L.
    Gates, Paul J.
    Street, Steven T. G.
    Wass, Duncan F.
    ACS CATALYSIS, 2015, 5 (10): : 5822 - 5826
  • [2] Ruthenium nitrosyl complexes [RuCl3(NO)(P-N)] bearing an oxazoline-derived P-N ligand (PHOX)
    da Silva, Juliana P.
    Lordello, Leonardo D.
    de Oliveira, Alfredo R. M.
    Back, Davi F.
    de Araujo, Marcio P.
    TRANSITION METAL CHEMISTRY, 2015, 40 (04) : 363 - 370
  • [3] Intramolecular Hydride Transfer Reactions in (Formazanate)Boron Dihydride Complexes
    Chang, Mu-Chieh
    Otten, Edwin
    ORGANOMETALLICS, 2016, 35 (04) : 534 - 542
  • [4] Synthesis and N-H Reductive Elimination Study of Dinuclear Ruthenium Imido Dihydride Complexes
    Takemoto, Shin
    Yamazaki, Yusuke
    Yamano, Takahiro
    Mashima, Daichi
    Matsuzaka, Hiroyuki
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (41) : 17027 - 17035
  • [5] Coordination study of ruthenium(II) complexes containing a mixed donor (P-N) ligand
    Lee, Chun-Chin
    Liu, Yi-Hung
    Peng, Shie-Ming
    Chou, Pi-Tai
    Chen, Jwu-Ting
    Liu, Shiuh-Tzung
    POLYHEDRON, 2012, 35 (01) : 23 - 30
  • [6] Reactions of ruthenium-aminophosphane complexes with diynes: P-N bond activation and formation of novel phosphaallyl, azaallyl, and aminocarbene complexes
    Pavlik, S
    Jantscher, F
    Dazinger, G
    Mereiter, K
    Kirchner, K
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, (05) : 1006 - 1021
  • [7] Some ruthenium hydride, dihydrogen, and dihydrogen-bonded complexes in catalytic reactions
    Lau, Chak Po
    Ng, Siu Man
    Jia, Guochen
    Lin, Zhenyang
    COORDINATION CHEMISTRY REVIEWS, 2007, 251 (17-20) : 2223 - 2237
  • [8] Synthesis, Characterization, and Reactivity of Ruthenium Hydride Complexes of N-Centered Triphosphine Ligands
    Phanopoulos, Andreas
    Brown, Neil J.
    White, Andrew J. P.
    Long, Nicholas J.
    Miler, Philip W.
    INORGANIC CHEMISTRY, 2014, 53 (07) : 3742 - 3752
  • [9] Protonation of 2H-Azaphosphirene Complexes: P-N Bond Activation and Ring-Expansion Reactions
    Helten, Holger
    Engeser, Marianne
    Gudat, Dietrich
    Schilling, Reinhold
    Schnakenburg, Gregor
    Nieger, Martin
    Streubel, Rainer
    CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (11) : 2602 - 2616
  • [10] Transfer Hydrogenation Reactions of Photoactivatable N, N′-Chelated Ruthenium(II) Arene Complexes
    Betanzos-Lara, Soledad
    Habtemariam, Abraha
    Sadler, Peter J.
    JOURNAL OF THE MEXICAN CHEMICAL SOCIETY, 2013, 57 (03) : 160 - 168
12345