Effects of fatty acid modified epoxy resin on long-chain epoxy and its physical properties

被引:6
|
作者
Kim, Hye Jin [1 ]
Yoon, Manseok [2 ]
Seo, Bongkuk [1 ]
Lim, Choong-Sun [1 ]
机构
[1] Korea Res Inst Chem Technol, Res Ctr Adv Specialty Chem, 45 Jongga Ro, Ulsan 44412, South Korea
[2] Seoul Natl Univ, Sch Mech & Aerosp Engn, Seoul, South Korea
关键词
epoxy; mechanical properties; plastics; polymer nanofiber; resins; MECHANICAL-PROPERTIES; CROSS-LINKING; NETWORKS; BEHAVIOR;
D O I
10.1002/pol.20230242
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The tendency of epoxy resins to form three-dimensional structures can make them brittle, which restricts their use in various applications even if they have great mechanical properties. Due to the expansion of epoxy resin application to electric automotives and aerospace as carbon fiber resistance plastics (CRFPs), it is desirable to synthesize epoxy resins that is more impact resistant. Herein, the synthesis of flexible epoxy resin FMER-F and FMER-J is reported. These epoxy resins were based on bisphenol F and J diglycidy ether. The dimeric fatty acid modified epoxy resins (FMERs) were synthesized by reacting acid anhydride modified epoxy resins (AMERs) with dimeric fatty acids. To obtain thermosetting epoxy polymers, the epoxy resin was mixed with a curing agent and an accelerator and, subsequently, it was cured at a high temperature. The mechanical properties of various epoxy polymers were analyzed to evaluate the change in the performance of the materials. The flexural strength of the composition with 10 parts per hundred resin (phr) of FMER-F increased by 21%. The impact strength of the composition with 30 phr of FMER-J increased by 27%. FMERs were found to be used as toughening agents in epoxy resins and composites because of their ability to enhance mechanical properties.
引用
收藏
页码:2194 / 2202
页数:9
相关论文
共 50 条
  • [1] Cyanate Ester Resin Modified with Hyperbranched Epoxy Resin and Its Properties
    Xu Z.
    Hou Y.
    Liu Z.
    Zhang Y.
    Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering, 2022, 38 (04): : 144 - 151
  • [3] Investigating the Effect of Modifier Chain Length on Insulation Properties of Polysulfide Modified Epoxy Resin
    Farajpour, Tohid
    Bayat, Yadollah
    Keshavarz, Mohammad Hossein
    Zanjirian, Ebrahim
    IRANIAN JOURNAL OF CHEMISTRY & CHEMICAL ENGINEERING-INTERNATIONAL ENGLISH EDITION, 2014, 33 (01): : 37 - 44
  • [4] Mechanical and Thermal Properties of Epoxy Resin Modified with Polyurethane
    Bakar, M.
    Duk, R.
    Przybylek, M.
    Kostrzewa, M.
    JOURNAL OF REINFORCED PLASTICS AND COMPOSITES, 2009, 28 (17) : 2107 - 2118
  • [5] Laboratory Investigation of the Properties of Asphalt Modified with Epoxy Resin
    Yu, Jianying
    Cong, Peiliang
    Wu, Shaopeng
    JOURNAL OF APPLIED POLYMER SCIENCE, 2009, 113 (06) : 3557 - 3563
  • [6] Mechanical properties of epoxy resin composites modified by epoxy styrene-butadiene latex
    Niu, Chunmei
    Du, Kaipeng
    Xu, Zheng
    Li, Zhiqiang
    Li, Tiantian
    Wang, Ruolin
    JOURNAL OF APPLIED POLYMER SCIENCE, 2023, 140 (26)
  • [7] The effects of modified zinc oxide nanoparticles on the mechanical/thermal properties of epoxy resin
    Baghdadi, Yasmine N.
    Youssef, Lucia
    Bouhadir, Kamal
    Harb, Mohammad
    Mustapha, Samir
    Patra, Digambara
    Tehrani-Bagha, Ali R.
    JOURNAL OF APPLIED POLYMER SCIENCE, 2020, 137 (43)
  • [8] Effects of Various Polyurethanes on the Mechanical and Structural Properties of an Epoxy Resin
    Kostrzewa, M.
    Hausnerova, B.
    Bakar, M.
    Siwek, E.
    JOURNAL OF APPLIED POLYMER SCIENCE, 2011, 119 (05) : 2925 - 2932
  • [9] Long-chain branched polypropylene obtained using an epoxy resin as crosslinking agent
    Guapacha, Jorge
    Valles, Enrique M.
    Quinzani, Lidia M.
    Failla, Marcelo D.
    POLYMER BULLETIN, 2017, 74 (06) : 2297 - 2318
  • [10] Long-chain branched polypropylene obtained using an epoxy resin as crosslinking agent
    Jorge Guapacha
    Enrique M. Vallés
    Lidia M. Quinzani
    Marcelo D. Failla
    Polymer Bulletin, 2017, 74 : 2297 - 2318