Synthesis, Crystal Structure and Thermal Decomposition of Copper(II) and Manganese(II) Complexes Based on Bipyridine Dicarboxylate and 1,10-Phenanthroline

被引：2

作者：

Jiang, X. ^{[1
]}

Tan, S. -h. ^{[1
]}

Chen, Z. -h. ^{[2
]}

Luo, H. ^{[1
]}

Sun, D. -w. ^{[1
]}

Zhong, G. -q. ^{[1
]}

机构：

[1] Southwest Univ Sci & Technol, Sch Mat & Chem, Mianyang, Peoples R China

[2] Southwest Univ, Sch Chem & Chem Engn, Chongqing, Peoples R China

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2023年 / 64卷 / 06期

关键词：

transition metal complex; hydrothermal synthesis; bipyridine dicarboxylic acid; crystal structure; thermal decomposition; luminescent property; ONE-DIMENSIONAL CHAIN; COORDINATION-COMPOUNDS; LIGAND; POLYMERS; LUMINESCENCE; NICKEL(II); CU(II);

D O I：

10.1134/S0022476623060057

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel transition metal complexes of the formulae [Cu(5,5 '-bpdc)(phen)](n) (1) and [Mn(6,6 ' bpdc)(phen)(H2O)]center dot H2O (2) (where phen = 1,10-phenanthroline, 5,5 '-H 2bpdc = 2,2 '-bipyridine-5,5 ' dicarboxylic acid, 6,6 '-H(2)bpdc = 2,2 '-bipyridine-6,6 '-dicarboxylic acid) were synthesized by hydrothermal reaction. The complexes were characterized by elemental analysis, X-ray diffraction, Fourier transform infrared spectroscopy, and thermogravimetry and differential scanning calorimetry. The X-ray crystallographic investigation reveals that 1 is a coordination polymer, and its asymmetric structural units are connected by oxygen atoms in the carboxyl group of 5,5 '-bpdc(2-) anion. 2 is a heptacoordination monomer complex with mono-capped trigonal prismatic configuration and its mononuclear molecules are connected by hydrogen bonds to form supramolecular structure. The result of fluorescence shows that 2 has fluorescent property.

引用

页码：1007 / 1020

页数：14

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