Acetamidinium bromoplumbate CH3C(NH2)2PbBr3 with 4H BaRuO3 structure

被引：2

作者：

Lee, Hyun-Jong ^{[1
]}

Lee, Eunji ^{[1
]}

Cha, Ji-Hyun ^{[2
]}

Jung, Duk-Young ^{[1
]}

机构：

[1] Sungkyunkwan Univ, Sungkyun Adv Inst Nanotechnol, Dept Chem, Suwon 16419, Gyeonggi Do, South Korea

[2] Chungnam Natl Univ, Dept Chem, 99 Daehak Ro, Daejeon 34134, South Korea

来源：

BULLETIN OF THE KOREAN CHEMICAL SOCIETY | 2023年 / 44卷 / 03期

关键词：

4H structure; acetamidinium bromide; BaRuO3; hybrid perovskite; lead bromide; ORGANIC-INORGANIC PEROVSKITES; LEAD HALIDE PEROVSKITES; CRYSTAL-STRUCTURE;

D O I：

10.1002/bkcs.12660

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Acetamidinium bromoplumbate, denoted (ACA)PbBr3, was synthesized from acetamidinium bromide and lead bromide in liquid medium under ambient atmosphere. The large radius of the acetamidinium group of (ACA)PbBr3 accommodates the 4H BaRuO3 structure, which has a hexagonal array of infinite face-shared and corner-shared [PbBr6](4-) units. (ACA)PbBr3 was characterized by single X-ray diffraction, chemical analyses, thermal analyses, H-1 NMR, and FT-IR spectroscopy.

引用

页码：230 / 235

页数：6

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