Two 2D transition metal coordination polymers based on 5-(1H-1,2,4-triazol-1-yl) isophthalic acid: synthesis, structure and magnetic properties

被引：7
|
作者：
Cao, Wei Wei [1 ]
Zhao, Fan [1 ]
Tian, Li [1 ]
机构：
[1] Tianjin Normal Univ, Coll Chem, Tianjin Key Lab Struct & Performance Funct Mol, Tianjin 300387, Peoples R China
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2023年 / 1285卷
基金：
中国国家自然科学基金;
关键词：
Crystal structure; 5-(1H-124-triazol-1-yl) isophthalic acid; Metal organic framework; Co(II) ion Mn(II) ion Magnetic property; ORGANIC FRAMEWORKS; COMPLEXES; CRYSTAL;
D O I：
10.1016/j.molstruc.2023.135489
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Two coordination polymers {[Co(TIA)(H2O)2]center dot 0.25H2O}n ( Co-1 ), and {[Mn(TIA)(H2O)2] center dot 0.5H2O}n ( Mn-2 ) were obtained solvothermally based on the exquisite combination of multidentate rigid linker 5-(1H-1,2,4-triazol-1-yl) isophthalic acid (H2TIA) and M(NO3)2 center dot 6H2O (M = Co(II), Mn(II)). The structures of 1-2 are both as 3,3-linked two-dimensional layers, which assemble into three dimensional supramolecular microporous structures by O -H center dot center dot center dot O hydrogen bonds. In addition, the static and/or dynamic magnetic characteristics of the two polymers were investigated.(c) 2023 Elsevier B.V. All rights reserved.
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页数：5
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