Innovations in p-n type heterostructure composite materials (La2O3/CeO2) for environmental contamination remediation: synthesis, characterization, and performance assessment

被引:2
作者
Kumar, Manoj [1 ]
Rahman, Atikur [1 ]
机构
[1] Natl Inst Technol Srinagar, Dept Met & Mat Engn, Srinagar 190006, India
关键词
Nanocomposites; Binary metal oxide; Photocatalyst; Methylene blue dye; Photocatalytic activity; PHOTOCATALYTIC DEGRADATION; METHYLENE-BLUE; LANTHANUM HYDROXIDE; NANOCOMPOSITE; NANOPARTICLES; OXIDATION; TIO2;
D O I
10.1007/s13399-023-04583-1
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The widespread presence of textile dye pollutants as byproducts in water bodies has raised serious concerns about the impact on the environment and human health. In this study, a nanocomposite material was made and its performance as a photocatalyst was looked at under different optimal conditions. The La2O3/CeO2 nanocomposite was created at room temperature using a simple and cost-effective co-precipitation method. In this study, different characterization tools, such as XRD, FE-SEM, UV-Drs, XPS, FT-IR, PL, and EDS, were used to look at the nanoparticles' structures, shapes, and optical properties. In the photocatalytic activity investigation, methylene blue (MB) dye was employed as a chosen pollutant, and illumination was delivered by a 450-Watt mercury vapor UV lamp. The La2O3/CeO2 nanocomposite removed 93% of the methylene blue dye in 100 min, compared to pure La2O3 and CeO2 nanoparticles (NPs). When the catalyst concentration was optimized at 25 mg/L and the pH was set to 12, 93% of the methylene blue was degraded in 100 min. The recyclability studies also revealed that the La2O3/CeO2 photocatalyst maintained an 84% degradation efficiency up to the fourth cycle, indicating that it is a stable and effective catalyst. Studies that used scavengers found that hydroxyl radicals were responsible for the breakdown of MB. Thus, La2O3/CeO2 photocatalysts may be regarded as a viable option for degrading organic dye pollutants in aqueous solutions.
引用
收藏
页码:23985 / 24006
页数:22
相关论文
共 64 条
  • [41] Comparison of sol-gel and co-precipitation methods on the structural properties and phase transformation of γ and α-Al2O3 nanoparticles
    Rajaeiyan, A.
    Bagheri-Mohagheghi, M. M.
    [J]. ADVANCES IN MANUFACTURING, 2013, 1 (02) : 176 - 182
  • [42] Ramjeyanthi N., 2018, Int. J. Interdiscip. Res. Innov, V6, P389
  • [43] Facile fabrication and application of SnO2-ZnO nanocomposites: insight into chain-like frameworks, heterojunctions and quantum dots
    Ren, Lanlan
    Chen, Dayong
    Hu, Zhixiang
    Gao, Ziming
    Luo, Zhigang
    Chen, Zhiwen
    Jiang, Yong
    Zhao, Bing
    Wu, C. M. Lawrence
    Shek, Chan-Hung
    [J]. RSC ADVANCES, 2016, 6 (85) : 82096 - 82102
  • [44] Parameters affecting the photocatalytic degradation of dyes using TiO2: a review
    Reza K.M.
    Kurny A.
    Gulshan F.
    [J]. Applied Water Science, 2017, 7 (4) : 1569 - 1578
  • [45] Synthesis of lanthanum carbonate nanoparticles via sonochemical method for preparation of lanthanum hydroxide and lanthanum oxide nanoparticles
    Salavati-Niasari, Masoud
    Hosseinzadeh, Ghader
    Davar, Fatemeh
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2011, 509 (01) : 134 - 140
  • [46] Saoud K., 2018, J. Mater. Environ. Sci, V9, P400, DOI [10.26872/jmes.2018.9.2.44, DOI 10.26872/JMES.2018.9.2.44]
  • [47] Visible light induced degradation of methylene blue using CeO2/V2O5 and CeO2/CuO catalysts
    Saravanan, R.
    Joicy, S.
    Gupta, V. K.
    Narayanan, V.
    Stephen, A.
    [J]. MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS, 2013, 33 (08): : 4725 - 4731
  • [48] Facile Synthesis of Fe3O4/ZnO Nanocomposite: Applications to Photocatalytic and Antibacterial Activities
    Shahsank, M.
    Naik, H. S. Bhojya
    Nagaraju, G.
    Keri, Rangappa S.
    Naik, M. Madhukara
    Lingaraju, K.
    [J]. JOURNAL OF ELECTRONIC MATERIALS, 2021, 50 (06) : 3557 - 3568
  • [49] La2O3-encapsulated SnO2 nanocrystallite-based photoanodes for enhanced DSSCs performance
    Shaikh, Shoyebmohamad F.
    Mane, Rajaram S.
    Joo, Oh-Shim
    [J]. DALTON TRANSACTIONS, 2015, 44 (07) : 3075 - 3081
  • [50] Efficient photocatalytic H2 evolution and Cr(VI) reduction under visible light using a novel Z-scheme SnIn4S8/CeO2 heterojunction photocatalysts
    Shen, Chun-Hui
    Chen, Yao
    Xu, Xin-Jie
    Li, Xue-Yang
    Wen, Xiao-Ju
    Liu, Zong-Tang
    Xing, Rong
    Guo, He
    Fei, Zheng-Hao
    [J]. JOURNAL OF HAZARDOUS MATERIALS, 2021, 416