Efficient Synthesis and Electrochemical Investigation of Co3O4:PdO/Pd Nanocomposite for High-Performance Supercapacitor Electrode Material

被引:0
作者
Shaheen, Irum [1 ,2 ]
Ahmad, Khuram Shahzad [1 ]
Zequine, Camila [3 ]
Gupta, Ram K. [3 ]
Thomas, Andrew G. [4 ,5 ]
Qureshi, Anjum [2 ]
Malik, Mohammad Azad [4 ,5 ]
Niazi, Javed H. [2 ]
Alarifi, Saud [6 ]
机构
[1] Fatima Jinnah Women Univ, Dept Environm Sci, Rawalpindi 46000, Pakistan
[2] Sabanci Univ, SUNUM Nanotechnol Res & Applicat Ctr, TR-34956 Istanbul, Turkiye
[3] Pittsburg State Univ, Dept Chem, 1701 South Broadway St, Pittsburg, KS 66762 USA
[4] Univ Manchester, Photon Sci Inst, Dept Mat, Alan Turing Bldg ,Oxford Rd, Manchester M13 9PL, England
[5] Univ Manchester, Sir Henry Royce Inst, Alan Turing Bldg,Oxford Rd, Manchester M13 9PL, England
[6] King Saud Univ, Coll Sci, Dept Zool, POB 2455, Riyadh 11451, Saudi Arabia
来源
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE | 2023年 / 220卷 / 14期
关键词
cobalt oxides; electrochemical energy storage; nanomaterials; nickel-palladium oxides; supercapacitors; ENERGY-STORAGE; COBALT OXIDE; METAL-OXIDES; GRAPHENE; NANOPARTICLES; FABRICATION; COMPOSITES; DEPOSITION; HYBRIDS;
D O I
10.1002/pssa.202300168
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Advancements in the metal oxides-based electrode material for the fabrication of supercapacitors have been an important focus of research in recent times. The electrochemical properties of electrode materials play a vital role in the excellent performance of the supercapacitor. In this regard, the doping of Co3O4 nanoparticles (NPs) with PdO/Pd using the ecofriendly extracted foliar reducing and stabilizing agent from Euphorbia cognata is analyzed. The as-synthesized Co3O4:PdO/Pd nanocomposite exhibits a multifaceted phase composition, characterized by a particle size of 22 nm and a bandgap energy of 2.28 eV. Remarkably, an obvious reduction in bandgap energy is observed, indicative of the heightened electrochemical performance of the Co3O4:PdO/Pd nanocomposite. Galvanostatic charge-discharge techniques elucidate impressive electrochemical properties, including a 202 F g(-1) specific capacitance and an exceptionally small resistance value of 1.04 & omega;. These findings not only infer efficient charge particle diffusion, but also signify an enhanced charge storage capacity. Thus, the outcomes of this study state the potential of functionalized foliar Co3O4:PdO/Pd nanocomposites as a promising choice for advanced electrode materials in supercapacitor applications. Importantly, this study highlights the significance of utilizing cost-effective and sustainable materials in the development of pioneering energy storage materials, contributing the advancement of materials field.
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页数:9
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