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Efficient Synthesis and Electrochemical Investigation of Co3O4:PdO/Pd Nanocomposite for High-Performance Supercapacitor Electrode Material
被引:0
作者:
Shaheen, Irum
[1
,2
]
Ahmad, Khuram Shahzad
[1
]
Zequine, Camila
[3
]
Gupta, Ram K.
[3
]
Thomas, Andrew G.
[4
,5
]
Qureshi, Anjum
[2
]
Malik, Mohammad Azad
[4
,5
]
Niazi, Javed H.
[2
]
Alarifi, Saud
[6
]
机构:
[1] Fatima Jinnah Women Univ, Dept Environm Sci, Rawalpindi 46000, Pakistan
[2] Sabanci Univ, SUNUM Nanotechnol Res & Applicat Ctr, TR-34956 Istanbul, Turkiye
[3] Pittsburg State Univ, Dept Chem, 1701 South Broadway St, Pittsburg, KS 66762 USA
[4] Univ Manchester, Photon Sci Inst, Dept Mat, Alan Turing Bldg ,Oxford Rd, Manchester M13 9PL, England
[5] Univ Manchester, Sir Henry Royce Inst, Alan Turing Bldg,Oxford Rd, Manchester M13 9PL, England
[6] King Saud Univ, Coll Sci, Dept Zool, POB 2455, Riyadh 11451, Saudi Arabia
来源:
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE
|
2023年
/
220卷
/
14期
关键词:
cobalt oxides;
electrochemical energy storage;
nanomaterials;
nickel-palladium oxides;
supercapacitors;
ENERGY-STORAGE;
COBALT OXIDE;
METAL-OXIDES;
GRAPHENE;
NANOPARTICLES;
FABRICATION;
COMPOSITES;
DEPOSITION;
HYBRIDS;
D O I:
10.1002/pssa.202300168
中图分类号:
T [工业技术];
学科分类号:
08 ;
摘要:
Advancements in the metal oxides-based electrode material for the fabrication of supercapacitors have been an important focus of research in recent times. The electrochemical properties of electrode materials play a vital role in the excellent performance of the supercapacitor. In this regard, the doping of Co3O4 nanoparticles (NPs) with PdO/Pd using the ecofriendly extracted foliar reducing and stabilizing agent from Euphorbia cognata is analyzed. The as-synthesized Co3O4:PdO/Pd nanocomposite exhibits a multifaceted phase composition, characterized by a particle size of 22 nm and a bandgap energy of 2.28 eV. Remarkably, an obvious reduction in bandgap energy is observed, indicative of the heightened electrochemical performance of the Co3O4:PdO/Pd nanocomposite. Galvanostatic charge-discharge techniques elucidate impressive electrochemical properties, including a 202 F g(-1) specific capacitance and an exceptionally small resistance value of 1.04 & omega;. These findings not only infer efficient charge particle diffusion, but also signify an enhanced charge storage capacity. Thus, the outcomes of this study state the potential of functionalized foliar Co3O4:PdO/Pd nanocomposites as a promising choice for advanced electrode materials in supercapacitor applications. Importantly, this study highlights the significance of utilizing cost-effective and sustainable materials in the development of pioneering energy storage materials, contributing the advancement of materials field.
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