Theoretical analysis of amperometric response towards PPO-based rotating disk bioelectrodes: Taylors series and hyperbolic function method

被引:6
作者
Silambuselvi, Vannathamizhan [1 ]
Rekha, Sekar [2 ]
Rani, Ramu Usha [3 ]
Rajendran, Lakshmanan [4 ,9 ]
Angaleeswari, Karuppiah [1 ]
Lyons, Michael E. G. [5 ,6 ,7 ,8 ]
机构
[1] Saraswathi Narayanan Coll, Dept Math, Madurai, India
[2] St Joseph Coll Engn, Dept Math, Chennai 602117, India
[3] Meenakshi Coll Engn, Dept Math, Chennai 600078, India
[4] AMET, Dept Math, Chennai 603112, India
[5] Univ Dublin, Trinity Coll Dublin, Sch Chem, Dublin 2, Ireland
[6] Univ Dublin, Trinity Coll Dublin, AMBER Natl Ctr, Dublin 2, Ireland
[7] Univ Dublin, Trinity Coll Dublin, Sch Chem, Dept Phys Chem, Dublin 2, Ireland
[8] Univ Dublin, Trinity Coll Dublin, AMBER Natl Ctr, Dublin 2, Ireland
[9] AMET Univ, Dept Math, Chennai 603112, Tamilnadu, India
关键词
Mathematical model; Polyphenol oxidase; Steady-State; Taylors series method; Hyperbolic function method; Rotating disk bioelectrodes; HOMOTOPY ANALYSIS METHOD; POLYPHENOL-OXIDASE; ENZYME ELECTRODE; TYROSINASE; BIOSENSOR; PHENOL; BEHAVIOR;
D O I
10.1016/j.ijoes.2023.100083
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A mathematical model for the electroenzymatic process of a rotating disk electrode in which polyphenol oxidase occurs is discussed. The model is related to a system of reaction-diffusion equations that includes a nonlinear factor relating to the enzymatic reaction's Michaelis-Menten kinetics. The approximate analytical techniques (Taylor's series and Hyperbolic function) are used to solve the nonlinear differential equations describing the diffusion-coupled enzymatic reactions. For all parameter values E(= L2) and 1( S ). Closed analytical equa-tions for the concentration of the substrate, the concentration of the product, and the related current response have been obtained. These analytical results are in good agreement when compared to simulation results ( Matlab program). The findings are reliable over the whole solution domain.
引用
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页数:8
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