Microwave-assisted co-gasification of mixed plastics and corn stover: A synergistic approach to produce clean hydrogen

Co-gasification of waste plastic and corn stover into hydrogen is an effective way of reducing hydrogen cost and carbon footprint. However, current gasification technologies are energy intensive and cannot accommodate flexible feedstock. Microwave gasification offers several advantages including higher H2 yield and enhanced selectivity to syngas over tars. This work presents parametric optimization study of microwave co-gasification of mixed plastics and corn stover for hydrogen-rich syngas. High hydrogen yields of 30.5 mmolH2/gfeedat 700 degrees C were obtained using a microwave reactor, as opposed to 0.9 mmolH2/gfeedat 700-950 degrees C with conventional heating. Hydrogen yields are >98% of the theoretical extractable hydrogen from feedstock. Microwaves enhanced plastic and corn stover synergy and reduced tar yields. H-poor carbon formation resulting from the dehydrogenation of tar and coke, and light olefins decomposition, triggered by the external microwave electric fields, allowed further cracking of intermediate hydrocarbons to produce additional H2.