A rational design of AIE-active fluorophore for the fingerprint optical detection

被引:10
|
作者
Yu, Le [1 ]
Xu, Yunjie [1 ]
Kim, Jungryun [1 ]
Lee, Jieun [1 ]
Kim, Jong Seung [1 ,2 ]
机构
[1] Korea Univ, Dept Chem, Seoul, South Korea
[2] Korea Univ, Dept Chem, Seoul 02841, South Korea
基金
新加坡国家研究基金会;
关键词
1,8-naphthalimide fluorophores; aggregation-induced emission; electron donating-pi conjugation-electron withdrawing structure; fingerprints detection; AGGREGATION-INDUCED EMISSION; FINGERMARK DETECTION; LATENT; RECOGNITION; PROBE; VISUALIZATION; NANOPOWDERS;
D O I
10.1002/bkcs.12681
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Fingerprints are one of the distinguishing characteristics of an individual, remaining unaltered throughout one's lifetime. It should be noted that fingerprints are significant and reliable evidence in various cases, such as criminal investigations, medical diagnosis, and public security. Thus, it is necessary to develop efficient techniques for fingerprints detection. Fortunately, the fluorescence emission of aggregation-induced emission (AIE) materials would increase instead of quenching upon excitation when they label fingerprints, which would clearly observe the structure of fingerprints. Herein, we devised a novel AIE-active fluorophore (NI-DB) with electron donor-pi bridge-electron acceptor (D-pi-A) structure based on the 1,8-naphthalimide. To our delight, after fingerprints fixed by cyanoacrylate glue fuming, NI-DB is capable of detecting and imaging fingerprints via its intrinsic fluorescence emission. And, with the aid of this technique, fingerprints on various object surfaces are successfully developed, suggesting the broad applicability.
引用
收藏
页码:516 / 522
页数:7
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