Future potential for lithium-sulfur batteries

被引:83
作者
Nakamura, Natsuki [1 ,3 ]
Ahn, Seongki [2 ,4 ]
Momma, Toshiyuki [1 ,2 ]
Osaka, Tetsuya [1 ,2 ]
机构
[1] Waseda Univ, Grad Sch Adv Sci & Engn, Shinju Ku, Tokyo 1698555, Japan
[2] Waseda Univ, Res Org Nano & Life Innovat, Shinju Ku, Tokyo 1620041, Japan
[3] Toshiba Co Ltd, Battery Div, Horikawa cho,Saiwai ku, Kawasaki 2128585, Japan
[4] Sangji Univ, Dept New Energy & Min Engn, Gangwon do, Wonju 26339, South Korea
关键词
Sulfur-based cathode; Carbon material; Gel; polymer electrolyte; Solid electrolyte; All-solid-state batteries; GEL POLYMER ELECTROLYTE; POLYPYRROLE COMPOSITE CATHODES; CARBON NANOTUBES COMPOSITE; IONIC LIQUID ELECTROLYTES; ELECTRICAL ENERGY-STORAGE; ELECTROCHEMICAL PROPERTIES; RECHARGEABLE BATTERIES; LI-ION; CONDUCTIVE POLYANILINE; DISCHARGE PERFORMANCE;
D O I
10.1016/j.jpowsour.2022.232566
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
With the increased adoption of electric vehicles globally and recent developments in international politics, the prices of cathode raw materials for lithium-ion batteries, such as nickel and cobalt, have continued to rise. These high raw material prices threaten to derail or delay the implementation of cleaner energy strategies. In view of this, research and development are actively being conducted toward the commercialization of lithium-sulfur batteries, which do not use rare metals as the cathode active material and have high energy density; in addi-tion, lithium and sulfur are naturally abundant. This review introduces the reaction principle of lithium-sulfur batteries to the latest research and development trends. The dissolution of intermediate polysulfides into the electrolyte, which is a fatal drawback of lithium-sulfur batteries, has been solved using various methods, such as compositing with carbon materials, polymer coating, and gel/polymer electrolytes. Therefore, all-solid-state lithium-sulfur batteries that offer improved safety and energy density can be expected to be futuristic batteries.
引用
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页数:15
相关论文
共 165 条
[1]   Highly conductive PEO-like polymer electrolytes [J].
Abraham, KM ;
Jiang, Z ;
Carroll, B .
CHEMISTRY OF MATERIALS, 1997, 9 (09) :1978-1988
[2]   Synthesis and electrochemical properties of a sulfur-multi walled carbon nanotubes composite as a cathode material for lithium sulfur batteries [J].
Ahn, Wook ;
Kim, Kwang-Bum ;
Jung, Kyu-Nam ;
Shin, Kyoung-Hee ;
Jin, Chang-Soo .
JOURNAL OF POWER SOURCES, 2012, 202 :394-399
[3]   High-rate operation of sulfur/mesoporous activated carbon composite electrode for all-solid-state lithium-sulfur batteries [J].
Ando, Taka ;
Sato, Yuta ;
Matsuyama, Takuya ;
Sakuda, Atsushi ;
Tatsumisago, Masahiro ;
Hayashi, Akitoshi .
JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 2020, 128 (05) :233-237
[4]  
Ansari R., 2006, E-J CHEM, V3, P186, DOI [10.1155/2006/860413, DOI 10.1155/2006/860413]
[5]   Electrolyte and solvent effects in PPy/DBS linear actuators [J].
Aydemir, Nihan ;
Kilmartin, Paul A. ;
Travas-Sejdic, Jadranka ;
Keskuela, Arko ;
Peikolainen, Anna-Liisa ;
Parcell, James ;
Harjo, Madis ;
Aabloo, Alvo ;
Kiefer, Rudolf .
SENSORS AND ACTUATORS B-CHEMICAL, 2015, 216 :24-32
[6]   Mesoporous Carbon Inter layers with Tailored Pore Volume as Polysulfide Reservoir for High-Energy Lithium-Sulfur Batteries [J].
Balach, Juan ;
Jaumann, Tony ;
Klose, Markus ;
Oswald, Steffen ;
Eckert, Juergen ;
Giebeler, Lars .
JOURNAL OF PHYSICAL CHEMISTRY C, 2015, 119 (09) :4580-4587
[7]   Diagnostic of failure mechanisms in Li/S rechargeable batteries using thermal micro-calorimetry technique applied to pouch and cylindrical type cells [J].
Barchasz, Celine ;
Boutafa, Laura ;
Mayousse, Eric ;
Chavillon, Benoit .
ELECTROCHIMICA ACTA, 2018, 292 :974-981
[8]   Stabilizing lithium metal using ionic liquids for long-lived batteries [J].
Basile, A. ;
Bhatt, A. I. ;
O'Mullane, A. P. .
NATURE COMMUNICATIONS, 2016, 7
[9]   Explorations toward the limit of utilizable pressures [J].
Bridgman, PW .
JOURNAL OF APPLIED PHYSICS, 1941, 12 (06) :461-469
[10]  
Bruce PG, 2012, NAT MATER, V11, P19, DOI [10.1038/NMAT3191, 10.1038/nmat3191]