Modulating microenvironments to enhance CO2 electroreduction performance

被引：89

作者：

Wang, Dan ^{[1
,2
]}

Mao, Junjun ^{[1
,2
]}

Zhang, Chenchen ^{[1
,2
]}

Zhang, Jiawei ^{[1
,2
]}

Li, Junshan ^{[3
]}

Zhang, Ying ^{[1
,2
]}

Zhu, Yongfa ^{[4
]}

机构：

[1] Jiangnan Univ, Sch Chem & Mat Engn, Key Lab Synthet & Biol Colloids, Minist Educ, Wuxi 214122, Jiangsu, Peoples R China

[2] Jiangnan Univ, Int Joint Res Ctr Photorespons Mol & Mat, Wuxi 214122, Jiangsu, Peoples R China

[3] Chengdu Univ, Inst Adv Study, Chengdu 610106, Peoples R China

[4] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China

来源：

ESCIENCE | 2023年 / 3卷 / 03期

基金：

中国国家自然科学基金;

关键词：

ECO2RR; Microstructure; Microenvironment; Key intermediates; Electrode-electrolyte interface; ELECTRODE-ELECTROLYTE INTERFACE; GAS-DIFFUSION ELECTRODES; ELECTROCHEMICAL REDUCTION; CARBON-DIOXIDE; ELECTROCATALYTIC CONVERSION; COPPER ELECTRODES; OXYGEN VACANCIES; OXIDATION-STATE; C-2; PRODUCTS; CU;

D O I：

10.1016/j.esci.2023.100119

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Microenvironments of the catalytic center, which play a vital role in adjusting electrocatalytic CO2 reduction reaction (ECO2RR) activity, have received increasing attention during the past few years. However, controllable microenvironment construction and the effects of multi-microenvironment variations for improving ECO2RR performance remain unclear. Herein, we summarize the representative strategies for tuning the catalyst and local microenvironments to enhance ECO2RR selectivity and activity. The multifactor synergetic effects of microenvironment regulation for enhancing CO2 accessibility, stabilizing key intermediates, and improving the performance of ECO2RR catalysts are discussed in detail, as well as perspectives on the challenges when investigating ECO2RR microenvironments. We anticipate that the discussions in this review will inspire further research in microenvironment engineering to accelerate the development of the ECO2RR for practical application.

引用

页数：18

共 161 条

[1] Poly-Amide Modified Copper Foam Electrodes for Enhanced Electrochemical Reduction of Carbon Dioxide [J].

Ahn, Sunyhik ;

Klyukin, Konstantin ;

Wakeham, Russell J. ;

Rudd, Jennifer A. ;

Lewis, Aled R. ;

Alexander, Shirin ;

Carla, Francesco ;

Alexandrov, Vitaly ;

Andreoli, Enrico .

ACS CATALYSIS, 2018, 8 (05) :4132-4142

[2] The role of in situ generated morphological motifs and Cu(i) species in C2+ product selectivity during CO2 pulsed electroreduction [J].

Aran-Ais, Rosa M. ;

Scholten, Fabian ;

Kunze, Sebastian ;

Rizo, Ruben ;

Roldan Cuenya, Beatriz .

NATURE ENERGY, 2020, 5 (04) :317-325

[3] Modulating the Electrode-Electrolyte Interface with Cationic Surfactants in Carbon Dioxide Reduction [J].

Banerjee, Soumyodip ;

Han, Xu ;

Thoi, V. Sara .

ACS CATALYSIS, 2019, 9 (06) :5631-5637

[4] Electrocatalytic and homogeneous approaches to conversion of CO2 to liquid fuels [J].

Benson, Eric E. ;

Kubiak, Clifford P. ;

Sathrum, Aaron J. ;

Smieja, Jonathan M. .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (01) :89-99

[5] Recent Technological Progress in CO2 Electroreduction to Fuels and Energy Carriers in Aqueous Environments [J].

Bevilacqua, Manuela ;

Filippi, Jonathan ;

Miller, Hamish A. ;

Vizza, Francesco .

ENERGY TECHNOLOGY, 2015, 3 (03) :197-210

[6] Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels [J].

Birdja, Yuvraj Y. ;

Perez-Gallent, Elena ;

Figueiredo, Marta C. ;

Gottle, Adrien J. ;

Calle-Vallejo, Federico ;

Koper, Marc T. M. .

NATURE ENERGY, 2019, 4 (09) :732-745

[7] Electrocatalysis at Organic-Metal Interfaces: Identification of Structure-Reactivity Relationships for CO2 Reduction at Modified Cu Surfaces [J].

Buckley, Aya K. ;

Lee, Michelle ;

Cheng, Tao ;

Kazantsev, Roman V. ;

Larson, David M. ;

Goddard, William A., III ;

Toste, F. Dean ;

Toma, Francesca M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (18) :7355-7364

[8] CO2 reduction on gas-diffusion electrodes and why catalytic performance must be assessed at commercially-relevant conditions [J].

Burdyny, Thomas ;

Smith, Wilson A. .

ENERGY & ENVIRONMENTAL SCIENCE, 2019, 12 (05) :1442-1453

[9] Theoretical Considerations on the Electroreduction of CO to C2 Species on Cu(100) Electrodes [J].

Calle-Vallejo, Federico ;

Koper, Marc T. M. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (28) :7282-7285

[10] Effects of the Catalyst Dynamic Changes and Influence of the Reaction Environment on the Performance of Electrochemical CO2 Reduction [J].

Chen, Jiayi ;

Wang, Lei .

ADVANCED MATERIALS, 2022, 34 (25)

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