Electrochemical Radical Reactions of Enol Acetates and Free Alcohols Directly Access to α-Alkoxylated Carbonyl Compounds

被引：5
作者：
Wu, Fan [1 ]
Guo, Yu [1 ]
Ren, Zihao [1 ]
Chen, Zixuan [1 ]
Liu, Xiaoqin [1 ]
Wang, Chang [2 ]
Rong, Liangce [1 ]
机构：
[1] Jiangsu Normal Univ, Sch Chem & Mat Sci, Xuzhou 221116, Jiangsu, Peoples R China
[2] Shandong First Med Univ, Shandong Acad Med Sci, Sch Pharmaceut Sci, Jinan 250117, Shandong, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 88卷 / 13期
关键词：
KETONES; INHIBITORS; CATALYSIS; FUNCTIONALIZATIONS; HYDROSILYLATION; HOMOLOGATION; OXIDATION; ACIDS;
D O I：
10.1021/acs.joc.3c00635
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Theefficient intermolecular alkoxylation reactions of variousenol acetates and different alcohols are developed in the electrochemicalprocess for the first time. Enol acetates derived from either aromatic,alkyl, or alicyclic ketones, and abundant free alcohols directly usedin this synthetic strategy, make this transformation very valuablein synthesis and application in the future.
引用
收藏
页码：8825 / 8834
页数：10
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