Design of Ion Channel Confined Binary Metal Cu-Fe Selenides for All-Climate, High-Capacity Sodium Ion Batteries

被引:0
作者
Chen, Dongliang [1 ]
Ye, Zhangran [2 ]
Jia, Peng [2 ]
Zhao, Zhenyun [1 ]
Lin, Jingwen [1 ]
Wang, Xu [1 ]
Ye, Zhizhen [1 ]
Li, Tongtong [3 ]
Zhang, Liqiang [2 ]
Lu, Jianguo [1 ]
机构
[1] Zhejiang Univ, Sch Mat Sci & Engn, State Key Lab Silicon & Adv Semicond Mat, Hangzhou 310027, Peoples R China
[2] Yanshan Univ, Sch Mat Sci & Engn, State Key Lab Metastable Mat Sci & Technol, Qinhuangdao 066004, Peoples R China
[3] Zhejiang Sci Tech Univ, Sch Mat Sci & Engn, Hangzhou 310018, Peoples R China
关键词
anode; full cell; sodium ion batteries; transition metal selenide; PERFORMANCE ANODE; CARBON;
D O I
10.1002/smtd.202301423
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Exploring special anode materials with high capacity, stable structure, and extreme temperature feasibility remains a great challenge in secondary sodium based energy systems. Here, a bimetallic Cu-Fe selenide nanosheet with refined nanostructure providing confined internal ion transport channels are reported, in which the structure improves the pseudocapacitance and reduces the charge transfer resistance for making a significant contribution to accelerating the reaction dynamics. The CuFeSe2 nanosheets have a high initial specific capacity of 480.4 mAh g-1 at 0.25 A g-1, showing impressively excellent rate performance and ultralong cycling life over 1000 cycles with 261.1 mAh g-1 at 2.5 A g-1. Meanwhile, it exhibits a good sodium storage performance at extreme temperatures from -20 degrees C to 50 degrees C, supporting at least 500 cycles. Besides, the CuFeSe2||Na3V2(PO4)3/C full cell delivers a high specific capacity of 168.5 mAh g-1 at 0.5 A g-1 and excellent feasibility for over 600 cycles long cycling. Additionally, the Na+ storage mechanisms are further revealed by ex situ X-ray diffraction (XRD) and in situ transmission electron microscopy (TEM) techniques. A feasible channelized structural design strategy is provided that inspires new instruction into the development of novel materials with high structural stability and low volume expansion rate toward the application of other secondary batteries. Cu-Fe selenides resembling confined channel structures are successfully prepared by one step hydrothermal method. Owing to the refined design of confined one dimensional ion channel, the sodium ion storage performance and stability of the Cu-Fe selenide are improved. The CuFeSe2 shows high specific capacities of 480.4 mAh g-1 at 0.25 A g-1 and ultralong cycling life over 1000 cycles with 261.1 mAh g-1 at 2.5 A ssg-1.image
引用
收藏
页数:11
相关论文
共 39 条
[11]   Mesoporous Cu2-xSe nanocrystals as an ultrahigh-rate and long-lifespan anode material for sodium-ion batteries [J].
Li, Yunjie ;
Sun, Xiucai ;
Cheng, Zhenjie ;
Xu, Xiao ;
Pan, Jun ;
Yang, Xianfeng ;
Tian, Fang ;
Li, Yanlu ;
Yang, Jian ;
Qian, Yitai .
ENERGY STORAGE MATERIALS, 2019, 22 :275-283
[12]   Design of hierarchical and mesoporous FeF3/rGO hybrids as cathodes for superior lithium-ion batteries [J].
Lian, Jiale ;
Wu, Yang ;
Guo, Yichuan ;
Zhao, Zhenyun ;
Zhang, Qinghua ;
Hou, Yang ;
Chen, Lingxiang ;
Lu, Bin ;
Pan, Xinhua ;
Ye, Zhizhen ;
Lu, Jianguo .
CHINESE CHEMICAL LETTERS, 2022, 33 (08) :3931-3935
[13]   Pomegranate-inspired porous SnSe/ZnSe@C anode: A stress-buffer nanostructure for fast and ultrastable sodium-ion storage [J].
Liang, Zhixin ;
Li, Qinghua ;
Zhang, Wang ;
Yu, Dandan ;
Zhang, Wei ;
Wu, Jiawei ;
Wang, Gaoyu ;
Fan, Wenbo ;
Wang, Junling ;
Huang, Shaoming .
JOURNAL OF ENERGY CHEMISTRY, 2022, 75 :369-377
[14]   Nanosheets-Assembled CuSe Crystal Pillar as a Stable and High-Power Anode for Sodium-Ion and Potassium-Ion Batteries [J].
Lin, Hezhe ;
Li, Malin ;
Yang, Xu ;
Yu, Dongxu ;
Zeng, Yi ;
Wang, Chunzhong ;
Chen, Gang ;
Du, Fei .
ADVANCED ENERGY MATERIALS, 2019, 9 (20)
[15]   Li+ ion insertion in TiO2 (anatase) .2. Voltammetry on nanoporous films [J].
Lindstrom, H ;
Sodergren, S ;
Solbrand, A ;
Rensmo, H ;
Hjelm, J ;
Hagfeldt, A ;
Lindquist, SE .
JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (39) :7717-7722
[16]   Multiple transition metals modulated hierarchical networks for high performance of metal-ion batteries [J].
Liu, Jie ;
Lou, Chenjie ;
Fu, Jipeng ;
Sun, Xuan ;
Hou, Jingrong ;
Ma, Jiwei ;
Chen, Yongjin ;
Gao, Xiang ;
Xu, Ligang ;
Wei, Qi ;
Tang, Mingxue .
JOURNAL OF ENERGY CHEMISTRY, 2022, 70 :604-613
[17]   FeSe2/nitrogen-doped carbon as anode material for Potassium-ion batteries [J].
Liu, Yanzhen ;
Yang, Chenghao ;
Li, Youpeng ;
Zheng, Fenghua ;
Li, Yijuan ;
Deng, Qiang ;
Zhong, Wentao ;
Wang, Gang ;
Liu, Tiezhong .
CHEMICAL ENGINEERING JOURNAL, 2020, 393
[18]   NASICON solid electrolyte coated by indium film for all-solid-state Li-metal batteries [J].
Liu, Yi-Jie ;
Fang, Ru-Yi ;
Mitlin, David .
TUNGSTEN, 2022, 4 (04) :316-322
[19]   Solid-Solution Anion-Enhanced Electrochemical Performances of Metal Sulfides/Selenides for Sodium-Ion Capacitors: The Case of FeS2-xSex [J].
Long, Yaqiong ;
Yang, Jing ;
Gao, Xin ;
Xu, Xuena ;
Fan, Weiliu ;
Hou, Shifeng ;
Qian, Yitai .
ACS APPLIED MATERIALS & INTERFACES, 2018, 10 (13) :10945-10954
[20]   Iron Selenide Microcapsules as Universal Conversion-Typed Anodes for Alkali Metal-Ion Batteries [J].
Lu, Shiyao ;
Wu, Hu ;
Xu, Siyuan ;
Wang, Yuankun ;
Zhao, Jianyun ;
Li, Yuhan ;
Abdelkader, Amr M. ;
Li, Jiao ;
Wang, Wei ;
Xi, Kai ;
Guo, Yuzheng ;
Ding, Shujiang ;
Gao, Guoxin ;
Kumar, Ramachandran Vasant .
SMALL, 2021, 17 (08)