Depleted uranium oxide supported nickel catalyst for autothermal CO2 methanation in non-adiabatic reactor under induction heating

被引:8
作者
Truong-Phuoc, Lai [1 ,2 ]
Nhut, Jean-Mario [1 ]
Vidal, Loic [3 ]
Duong-Viet, Cuong [1 ,2 ]
Sall, Secou [1 ]
Petit, Corinne [1 ]
Sutter, Christophe [1 ]
Arab, Mehdi [4 ]
Jourdan, Alex [4 ]
Pham-Huu, Cuong [1 ]
机构
[1] Univ Strasbourg, Inst Chem & Proc Energy Environm & Hlth ICPEES, ECPM, CNRS,UMR 7515, 25 Rue Becquerel, F-67087 Strasbourg 02, France
[2] BlackLeaf SAS, 210 Rue Geiler Kaysersberg, F-67400 Illkirch Graffenstaden, France
[3] Univ Haute Alsace, Inst Mat Sci Mulhouse, CNRS, UMR 7361,IS2M, 15 Rue Jean Starcky,BP 2488, F-68057 Mulhouse, France
[4] ORANO Tricastin, Direct Rech & Dev, Site TRICASTIN BP 16, F-60761 Pierrelatte, France
来源
JOURNAL OF ENERGY CHEMISTRY | 2023年 / 85卷
关键词
CO; 2; methanation; Auto-methanation; Induction heating; Depleted uranium oxide; Electrification process; Operando DRIFTS; HYDROGEN-PRODUCTION; UP-CONVERSION; GAS; NANOPARTICLES; PYROLYSIS;
D O I
10.1016/j.jechem.2023.06.035
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Undoped nickel-based catalysts supported on depleted uranium oxide allow one to carry out CO2 methanation process under extremely low reaction temperature under atmospheric pressure and powered by a contactless induction heating. By adjusting the reaction conditions, the catalyst is able to perform CO2 methanation reaction under autothermal process operated inside a non-adiabatic reactor, without any external energy supply. Such autothermal process is possible thanks to the high apparent density of the UOx which allows one to confine the reaction heat in a small catalyst volume in order to confine the exothermicity of the reaction inside the catalyst and to operate the reaction at equilibrium heat in-heat out. Such autothermal operation mode allows one to significantly reduce the complexity of the process compared to that operated using adiabatic reactor, where complete insulation is required to prevent heat disequilibrium, in order to reduce as much as possible, the heat exchange with the external medium. The catalyst displays an extremely high stability as a function of time on stream as no apparent deactivation. It is expected that such new catalyst with unprecedented catalytic performance could open new era in the field of heterogeneous catalysis where traditional supports show their limitations to operate catalytic processes under severe reaction conditions. & COPY; 2023 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press. All rights reserved.
引用
收藏
页码:310 / 323
页数:14
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