SYNTHESIS, STRUCTURE, AND MECHANISM OF HALF-SANDWICH RUTHENIUM COMPLEX CONTAINING ORTHO-CARBORANE-1,2-DITHIOLATE LIGAND AND 1-PHENYL-2-PROPYN-1-OL

被引：1

作者：

Hu, J. R. ^{[1
,2
]}

Zhao, S. Q. ^{[3
]}

Wang, J. H. ^{[4
]}

Sun, S. Q. ^{[1
,2
]}

Miao, C. P. ^{[5
,6
]}

机构：

[1] Jiaxing Nanhu Univ, Coll Adv Mat Engn, Jiaxing, Zhejiang, Peoples R China

[2] Jiaxing Key Lab Preparat & Applicat Adv Mat Energy, Jiaxing, Zhejiang, Peoples R China

[3] Jiangxi Open Univ, Nanchang, Jiangxi, Peoples R China

[4] Jiaxing Nanhu Univ, Coll Humanities & Arts, Jiaxing, Zhejiang, Peoples R China

[5] Jiaxing Univ, Coll Biol & Chem Engn, Jiaxing, Zhejiang, Peoples R China

[6] Zhejiang Engn Res Ctr Arene Sulfon Acid, Hangzhou, Zhejiang, Peoples R China

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2023年 / 64卷 / 12期

基金：

中国国家自然科学基金;

关键词：

ruthenium complexes; o-carborane; 1-phenyl-2-propyn-1-ol; synthesis; structure; B-H ACTIVATION; 1,2-DICARBA-CLOSO-DODECABORANE-1,2-DITHIOLATE LIGANDS; MEDICINAL CHEMISTRY; DRUG DISCOVERY; REACTIVITY; PHENYLACETYLENE; (P-CYMENE)RU; CARBORANES; BONDS;

D O I：

10.1134/S0022476623120053

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel complex (p-cymene)Ru(S2C2B10H9)(PhCH=CCH2OCH(Ph)C equivalent to CH)& sdot;CH2Cl2 based on the ortho- carborane-1,2-dithiolate ligand and 1-phenyl-2-propyn-1-ol has been synthesized successfully and characterized by IR, NMR, MS, elemental analysis and single-crystal X-ray diffraction. The complex crystallizes in monoclinic system, space group P2(1)/n with: a = 10.221(4) & Aring;, b = 14.912(6) & Aring;, c = 24.182(10) & Aring;, alpha = 90.00 degrees , beta = 99.096(6)degrees , gamma = 90.00 degrees , C31H40B10Cl2ORuS2 , M-r = 772.82, V = 3639(3) & Aring;3 , D-c = 1.410 g/cm(3) , Z = 4, F(000) = 1576, mu(MoK alpha) = 0.719 mm(-1) , R = 0.0600 and wR = 0.1561 for 5463 observed reflections (I > 2 sigma(I)). Structural analysis shows that there are the coordination of C=C bond, the formation of C-S bod, and metal-induced B-H activation with the formation of Ru-B bond.

引用

页码：2343 / 2350

页数：8

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