Stable all-solid-state sodium-sulfur batteries for low-temperature operation enabled by sodium alloy anode and confined sulfur cathode

被引:26
|
作者
Jhang, Li-Ji
Wang, Daiwei [2 ]
Silver, Alexander [3 ]
Li, Xiaolin [1 ,4 ]
Reed, David [4 ]
Wang, Donghai [2 ]
机构
[1] Penn State Univ, Dept Chem Engn, University Pk, PA 16802 USA
[2] Penn State Univ, Dept Mech Engn, University Pk, PA 16802 USA
[3] Penn State Univ, Dept Mat Sci & Engn, University Pk, PA 16802 USA
[4] Pacific Northwest Natl Lab, Energy & Environm Directorate, Richland, WA 99352 USA
关键词
Na-S batteries; All-solid-state batteries; Na alloy anodes; Sulfur composite cathodes; RECENT PROGRESS; PERFORMANCE; ELECTROLYTES; ELECTRODES; LITHIUM; SN; STORAGE; NA3PS4; CARBON; METAL;
D O I
10.1016/j.nanoen.2022.107995
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
All-solid-state sodium-sulfur (Na-S) batteries are promising for stationary energy storage devices because of their low operating temperatures (less than 100 degrees C), improved safety, and low-cost fabrication. Using Na alloy instead of Na metal as an anode in Na-S batteries can prevent dendrite growth and improve interfacial stability between the anode and solid electrolytes to achieve long-cycling stability. A high-sulfur content cathode possessing high sulfur utilization is also important to enable an energy-dense Na-S battery. In this work, we studied Na-Sb and Na-Sn alloy anodes and demonstrated the superiority of Na3Sb alloy undergoing a stable Na alloying/dealloying process at 0.04 mA cm-2 for over 500 h. Combining the optimized Na3Sb alloy anode with sulfur-carbon composites prepared by the vapor deposition approach, the full cell shows a high sulfur specific capacity and improved rate performance. Moreover, the all-solid-state Na alloy-S battery can deliver a high initial discharge specific capacity of 1377 mAh g-1 and maintain good capacity retention of 70 % after 180 cycles at 60 degrees C. Post -cycle characterizations show that both the anode and cathode perform a reversible discharge/charge process after the 1st cycle, and the cathode undergoes significantly rearranged distributions of carbon and solid-state electrolytes after 180 cycles due to severe volume change induced by repeated sodiation/desodiation process. Data availability: Data will be made available on request.
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页数:8
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