Study of furfural derivatives as a possible green corrosion inhibitor for mild steel in CO2-saturated formation water

被引:31
作者
Cunha, Jessica Nogueira da [1 ]
Evangelista, Brenno Danho Veras [1 ]
Xavier, Amanda Vieira [1 ]
Silva, Talis Uelisson da [1 ]
Oliveira, Sanair Massafra de [2 ]
Araujo, Joyce Rodrigues de [2 ]
Archanjo, Braulio Soares [2 ]
Machado, Sergio de Paula [1 ]
Rezende, Michelle Jakeline Cunha [1 ]
Almeida, Tatiana das Chagas [3 ]
Mattos, Oscar Rosa [3 ]
'Elia, Eliane [1 ]
机构
[1] Univ Fed Rio De Janeiro, Inst Quim, BR-21941909 Rio De Janeiro, RJ, Brazil
[2] Inst Nacl Metrol, Qualidade & Tecnol INMETRO, BR-25250020 Rio De Janeiro, RJ, Brazil
[3] Univ Fed Rio De Janeiro, Laborato rio Ensaios Destrut Corrosa & Soldagem L, COPPE, BR-21945970 Rio De Janeiro, RJ, Brazil
关键词
Mild steel; Green corrosion inhibitor; In -situ synthesis; Furfural derivatives; CO 2-saturated brines; CARBON-STEEL; HCL; IMPEDANCE; IRON; BENZIMIDAZOLE; ADSORPTION; CHEMISTRY; MECHANISM; ENERGIES; SURFACE;
D O I
10.1016/j.corsci.2022.110907
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The anticorrosive activity of furfural derivatives, by ex-situ and in-situ syntheses, on mild steel immersed in CO2- saturated formation water solution was evaluated using mass loss measurements, polarization curves, X-ray photoelectron spectroscopy, quantum chemical calculation, and electrochemical impedance. Furfural thio-semicarbazone presented inhibition efficiency reaching 90.2% for 72 h in immersion. The same molecule, synthesized in-situ by the mixture of the precursors in the corrosive medium, also produced good efficiency, 82.2% for 24 h of immersion, but it decreased over the time due to incomplete conversion of the precursors in furfural thiosemicarbazone.
引用
收藏
页数:15
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