A sustainably produced hydrochar from pomegranate peels for the purification of textile contaminants in an aqueous medium

被引:35
作者
Akkari, Imane [1 ]
Spessato, Lucas [2 ]
Graba, Zahra [1 ]
Bezzi, Nacer [1 ]
Kaci, Mohamed Mehdi [3 ]
机构
[1] Univ Bejaia, Mat Technol & Proc Engn Lab LTMGP, Bejaia 06000, Algeria
[2] Univ Estadual Maringa, Dept Chem, Ave Colombo 5790, Maringa, PR, Brazil
[3] USTHB, Lab React Engn, Fac Mech & Proc Engn, BP 32, Algiers 16111, Algeria
关键词
Hydrochar; Pomegranate peels; Adsorption; Basic red 46 dye; ACTIVATED CARBON; METHYLENE-BLUE; HYDROTHERMAL CARBONIZATION; WASTE-WATER; CATIONIC DYES; EFFECTIVE REMOVAL; MALACHITE GREEN; SURFACE-AREA; BASIC DYE; ADSORPTION;
D O I
10.1016/j.scp.2022.100924
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hydrothermal Carbonization presents an easy, inexpensive, and eco-friendly method to convert waste from natural resources into sustainable materials. This study used the Hydrothermal Car-bonization (HTC) approach to make hydrochar from locally available pomegranate peels. Several analytical tools were employed for its characterization, including elemental analysis, X-ray Dif-fraction, micro-Raman, Fourier Transform Infrared Spectroscopy, Scanning Electron Microscopy, Textual analysis, pHpzc, and Boehm titration. The produced hydrochar performed well in remov-ing cationic dye Basic Red 46 (BR46) from an aqueous medium, adsorbing 286.90 and 367.72 mg g-1 within only 5 and 60 min, respectively, at ideal circumstances. The Freundlich model was the most appropriate for the equilibrium data, whilst the pseudo-second-order model was found closest to the kinetic data (R2 = 0.980; Delta qe = 7.934%). Per the thermodynamic study, the dye adsorption was spontaneous (Delta G degrees < 0) and endothermic (Delta H degrees = 32.777 kJ mol-1). Furthermore, the prepared hydrochar (HCPP) has revealed good reusability, as it can be reused up to five times without losing its effectiveness. In summary, the outcomes obtained revealed that HCPP could be an effective and eco-friendly adsorbent for the treatment of colored wastewater.
引用
收藏
页数:16
相关论文
共 92 条
[1]  
Akkari I., 2022, BIOMASS CONVERS BIOR, P1
[2]   Effective removal of cationic dye on activated carbon made from cactus fruit peels: a combined experimental and theoretical study [J].
Akkari, Imane ;
Graba, Zahra ;
Bezzi, Nacer ;
Kaci, Mohamed Mehdi ;
Merzeg, Farid Ait ;
Bait, Nadia ;
Ferhati, Azedine ;
Dotto, Guilherme L. ;
Benguerba, Yacine .
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2023, 30 (02) :3027-3044
[3]   Raw pomegranate peel as promise efficient biosorbent for the removal of Basic Red 46 dye: equilibrium, kinetic, and thermodynamic studies [J].
Akkari, Imane ;
Graba, Zahra ;
Bezzi, Nacer ;
Merzeg, Farid Ait ;
Bait, Nadia ;
Ferhati, Azedine .
BIOMASS CONVERSION AND BIOREFINERY, 2023, 13 (09) :8047-8060
[4]   Facile synthesis of zinc oxide nanoparticles loaded activated carbon as an eco-friendly adsorbent for ultra-removal of malachite green from water [J].
Altintig, Esra ;
Yenigun, Merve ;
Sari, Ahmet ;
Altundag, Huseyin ;
Tuzen, Mustafa ;
Saleh, Tawfik A. .
ENVIRONMENTAL TECHNOLOGY & INNOVATION, 2021, 21
[5]   Preparation, characterization and evaluation of bio-based magnetic activated carbon for effective adsorption of malachite green from aqueous solution [J].
Altintig, Esra ;
Onaran, Muge ;
Sari, Ahmet ;
Altundag, Huseyin ;
Tuzen, Mustafa .
MATERIALS CHEMISTRY AND PHYSICS, 2018, 220 :313-321
[6]   Effective removal of methylene blue from aqueous solutions using magnetic loaded activated carbon as novel adsorbent [J].
Altintig, Esra ;
Altundag, Huseyin ;
Tuzen, Mustafa ;
Sari, Ahmet .
CHEMICAL ENGINEERING RESEARCH & DESIGN, 2017, 122 :151-163
[7]   Recent Progress on Biosorption of Heavy Metals from Liquids Using Low Cost Biosorbents: Characterization, Biosorption Parameters and Mechanism Studies [J].
Arief, Vicentius Ochie ;
Trilestari, Kiki ;
Sunarso, Jaka ;
Indraswati, Nani ;
Ismadji, Suryadi .
CLEAN-SOIL AIR WATER, 2008, 36 (12) :937-962
[8]  
Atmani F., 2022, BIOMASS CONVERS BIOR, P1
[9]   Influence of milling on the adsorption ability of eggshell waste [J].
Balaz, Matej ;
Ficeriova, Jana ;
Briancin, Jaroslav .
CHEMOSPHERE, 2016, 146 :458-471
[10]   Adsorptive removal of chromium(VI) from aqueous solution unto groundnut shell [J].
Bayuo, Jonas ;
Pelig-Ba, Kenneth Bayetimani ;
Abukari, Moses Abdullai .
APPLIED WATER SCIENCE, 2019, 9 (04)