Deep Eutectic Solvents for Biotechnology Applications

被引:20
作者
Morozova, Olga V. [1 ]
Vasil'eva, Irina S. [1 ]
Shumakovich, Galina P. [1 ]
Zaitseva, Elena A. [2 ]
Yaropolov, Alexander I. [1 ]
机构
[1] Russian Acad Sci, Bach Inst Biochem, Fed Res Ctr Fundamental Bases Biotechnol, Moscow 119071, Russia
[2] Lomonosov Moscow State Univ, Fac Chem, Moscow 119991, Russia
基金
俄罗斯基础研究基金会;
关键词
deep eutectic solvent; biotechnology; delignification; extraction; biocatalysis; bioplastic; TEMPERATURE MIXTURES LTTMS; ACTIVE PHARMACEUTICAL INGREDIENTS; IONIC LIQUIDS; CHOLINE-CHLORIDE; LIGNOCELLULOSIC BIOMASS; PHYSICAL-PROPERTIES; PHYSICOCHEMICAL PROPERTIES; LIGNIN NANOPARTICLES; PEROXIDASE-ACTIVITY; AQUEOUS-SOLUTIONS;
D O I
10.1134/S0006297923140092
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Deep eutectic solvents (DESs) are an alternative to traditional organic solvents and ionic liquids and meet the requirements of "green" chemistry. They are easy to prepare using low-cost constituents, are non-toxic and biodegradable. The review analyzes literature on the use of DES in various fields of biotechnology, provides data on the types of DESs, methods for their preparation, and properties. The main areas of using DESs in biotechnology include extraction of physiologically active substances from natural resources, pretreatment of lignocellulosic biomass to improve enzymatic hydrolysis of cellulose, production of bioplastics, as well as a reaction medium for biocatalytic reactions. The aim of this review is to summarize available information on the use of new solvents for biotechnological purposes.
引用
收藏
页码:S150 / S175
页数:26
相关论文
共 174 条
[1]   Eutectic-based ionic liquids with metal-containing anions and cations [J].
Abbott, Andrew P. ;
Barron, John C. ;
Ryder, Karl S. ;
Wilson, David .
CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (22) :6495-6501
[2]   Application of hole theory to define ionic liquids by their transport properties [J].
Abbott, Andrew P. ;
Harris, Robert C. ;
Ryder, Karl S. .
JOURNAL OF PHYSICAL CHEMISTRY B, 2007, 111 (18) :4910-4913
[3]   Thermoplastic starch-polyethylene blends homogenised using deep eutectic solvents [J].
Abbott, Andrew P. ;
Abolibda, Tariq Z. ;
Qu, Wanwan ;
Wise, William R. ;
Wright, Luka A. .
RSC ADVANCES, 2017, 7 (12) :7268-7273
[4]   Glycol based plasticisers for salt modified starch [J].
Abbott, Andrew P. ;
Abolibda, Tariq Z. ;
Davis, Stefan J. ;
Emmerling, Franziska ;
Lourdin, Denis ;
Leroy, Eric ;
Wise, William R. .
RSC ADVANCES, 2014, 4 (76) :40421-40427
[5]   Salt modified starch: sustainable, recyclable plastics [J].
Abbott, Andrew P. ;
Ballantyne, Andrew D. ;
Conde, Jesus Palenzuela ;
Ryder, Karl S. ;
Wise, William R. .
GREEN CHEMISTRY, 2012, 14 (05) :1302-1307
[6]   Double layer effects on metal nucleation in deep eutectic solvents [J].
Abbott, Andrew P. ;
Barron, John C. ;
Frisch, Gero ;
Gurman, Stephen ;
Ryder, Karl S. ;
Fernando Silva, A. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (21) :10224-10231
[7]   Glycerol eutectics as sustainable solvent systems [J].
Abbott, Andrew P. ;
Harris, Robert C. ;
Ryder, Karl S. ;
D'Agostino, Carmine ;
Gladden, Lynn F. ;
Mantle, Mick D. .
GREEN CHEMISTRY, 2011, 13 (01) :82-90
[8]   Preparation of novel, moisture-stable, Lewis-acidic ionic liquids containing quaternary ammonium salts with functional side chains [J].
Abbott, AP ;
Capper, G ;
Davies, DL ;
Munro, HL ;
Rasheed, RK ;
Tambyrajah, V .
CHEMICAL COMMUNICATIONS, 2001, (19) :2010-2011
[9]   Deep eutectic solvents formed between choline chloride and carboxylic acids: Versatile alternatives to ionic liquids [J].
Abbott, AP ;
Boothby, D ;
Capper, G ;
Davies, DL ;
Rasheed, RK .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (29) :9142-9147
[10]   Ionic liquids based upon metal halide/substituted quaternary ammonium salt mixtures [J].
Abbott, AP ;
Capper, G ;
Davies, DL ;
Rasheed, R .
INORGANIC CHEMISTRY, 2004, 43 (11) :3447-3452