Enhancing dye-sensitized solar cell performance by employing an innovative WSe2:Zn counter electrode for improved electrocatalytic activity

被引:17
作者
Abbood, Manal Abdulwahid [1 ]
Saleh, Ebraheem Abdu Musad [2 ]
Kumar, Abhinav [3 ]
Rodrigues, Paul [4 ]
Askar, Shavan [5 ]
Alawsi, Taif [6 ]
Alawadi, Ahmed [7 ,8 ,9 ]
Alsalamy, Ali [10 ]
机构
[1] Univ Technol Iraq, Appl Phys Dept, Baghdad, Iraq
[2] Prince Sattam Bin Abdulaziz Univ, Coll Sci & Humanities Al Kharj, Dept Chem, Al Kharj 11942, Saudi Arabia
[3] Ural Fed Univ, Dept Nucl & Renewable Energy, Ekaterinburg 620002, Russia
[4] King Khalid Univ, Coll Comp Sci, Dept Comp Engn, Al Faraa, Saudi Arabia
[5] Erbil Polytech Univ, Tech Engn Coll, Erbil, Iraq
[6] Al Ayen Univ, Sci Res Ctr, Thi Qar, Iraq
[7] Islamic Univ, Coll Tech Engn, Najaf, Iraq
[8] Islamic Univ, Coll Tech Engn, Al Diwaniyah, Iraq
[9] Islamic Univ, Coll Tech Engn, Babylon, Iraq
[10] Imam Jaafar Al Sadiq Univ, Coll Tech Engn, Al Muthanna 66002, Iraq
关键词
Dye-sensitized solar cell; Counter electrode; WSe; 2; Nanoflakes; THIN-FILM; BAND-GAP; STRAIN; SNO2;
D O I
10.1016/j.mssp.2023.108015
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
In this research, we introduced a novel counter electrode (CE) for dye-sensitized solar cells (DSSCs) based on crystalline WSe2 doped with Zn impurities. The crystalline nature of these CEs was confirmed through X-ray diffraction (XRD) analysis. Additionally, we demonstrated that Zn dopants significantly enhances the electrochemical and electrocatalytic properties of the CEs. These improvements were verified using electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV), and Tafel analysis with iodine-based electrolytes. Collectively, these enhancements resulted in a remarkable 42 % increase in DSSC efficiency, improving it from 5.78 % to 8.19 % under optimized conditions. Notably, this surpassed the performance of platinum-based CEs, which achieved 7.66 % efficiency. The proposed CE holds great promise for advancing DSSCs by elevating their efficiency and reducing fabrication costs.
引用
收藏
页数:9
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