Cypermethrin insecticide detection by surface-enhanced Raman spectroscopy

被引:3
作者
Puente, Carlos [2 ]
Pineda, Nayely [3 ]
Lopez, Israel [1 ,2 ]
机构
[1] Univ Autonoma Nuevo Leon UANL, Fac Ciencias Quim, Ctr Invest Biotecnol & Nanotecnol, Lab Nanociencias & Nanotecnol, Autopistaal Aeropuerto Int Mariano Escobedo Km 10,, Apodaca 66629, Mexico
[2] Univ Autonoma Nuevo Leon UANL, Fac Ciencias Quim, Ctr Invest Biotecnol & Nanotecnol, Lab Nanociencias & Nanotecnol, Apodaca, Mexico
[3] SC CIMAV, Ctr Invest Mat Avanzados, Unidad Monterrey, Apodaca, Mexico
关键词
SERS; insecticide detection; silver; morphology effect; cypermethrin; PESTICIDE DETECTION; SILVER;
D O I
10.1002/jctb.7392
中图分类号
Q81 [生物工程学(生物技术)]; Q93 [微生物学];
学科分类号
071005 ; 0836 ; 090102 ; 100705 ;
摘要
BACKGROUND: The common practice worldwide to get rid of unwanted crawling and flying insects using commercially available insecticides represents a potential danger of leakage of containers, and pollution of water and soil that can harm both target and non-target species. Cypermethrin, a synthetic pyrethroid, is one of the most widely used household broad-spectrum insecticides. RESULTS: Silver nanosphere (AgNS)-, triangular nanoplate (AgNT)- and nanodecahedra (AgND)-based substrates for surfaceenhanced Raman spectroscopy (SERS) were tested, showing that AgND led to high detection sensitivity of cypermethrin with no previous sample treatment, even at low laser power (0.1 mW). Also, reproducibility tests were carried out with one substrate as well as with different substrates. CONCLUSIONS: This study showed that AgND substrates are sufficiently sensitive to detect cypermethrin by SERS using a 780 nm laser, in a complex matrix with no photo-bleaching and without the need for sample treatment. (c) 2023 Society of Chemical Industry (SCI).
引用
收藏
页码:1863 / 1867
页数:5
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