A Configuration Entropy Enabled High-Performance Polyanionic Cathode for Sodium-Ion Batteries

被引：48
作者：
Li, Meng [1 ]
Sun, Chen [1 ]
Yuan, Xuanyi [2 ]
Li, Yang [1 ]
Yuan, Yifei [3 ]
Jin, Haibo [1 ]
Lu, Jun [4 ]
Zhao, Yongjie [1 ]
机构：
[1] Beijing Inst Technol, Sch Mat Sci & Engn, Beijing Key Lab Construct Tailorable Adv Funct Mat, Beijing 100081, Peoples R China
[2] Renmin Univ China, Beijing Key Lab Optoelect Funct Mat & Micronano De, Dept Phys, Beijing 100872, Peoples R China
[3] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou 325035, Zhejiang, Peoples R China
[4] Zhejiang Univ, Coll Chem & Biol Engn, Hangzhou 310027, Peoples R China
来源：
ADVANCED FUNCTIONAL MATERIALS | 2024年 / 34卷 / 21期
基金：
中国国家自然科学基金;
关键词：
configuration entropy; high energy density; long-life cycling stability; NASICON cathode; sodium ion batteries; ELECTRODE MATERIALS; NA3V2(PO4)(3);
D O I：
10.1002/adfm.202314019
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Polyanionic sodium ion cathodes have attracted lots of concern because of their excellent structural stability. However, the low specific capacity is still a pressing issue hampering their practical application. In this work, a medium-entropy NASICON-structure cathode Na3.5V0.5Mn0.5Fe0.5Ti0.5(PO4)(3) (Me-NVMP) is proposed. The Me-NVMP achieves a highly reversible specific capacity of 165.8 mAh g(-1) (1.8-4.4 V vs Na+/Na) at 0.1 C via the stepwise redox reactions of Ti3+/Ti4+-Fe2+/Fe3+, V3+/V4+-Mn2+/Mn3+, and V4+/V5+-Mn3+/Mn4+. More impressively, the Me-NVMP yields super rate capability and cycling stability via the regulation of configuration entropy in NASICON. Specifically, the Me-NVMP cathode can preserve a capacity retention of 83.5% after 10,000 cycles at 100 C (17 A g(-1)). Furthermore, excellent cycling performance even at the temperature of 0 degrees C (capacity retention of 93.45% at 20 C after 1000 cycles) is also demonstrated. In situ X-ray diffraction analysis reveals that the enhanced performance can be mainly attributed to the solid-solution-type Na+ storage behavior in Me-NVMP. Moreover, issues such as Jahn-Teller distortion of Mn3+ and irreversible structural change at high voltage (>4.0 V vs Na+/Na) are effectively mitigated. This work inspires a new strategy to design high-performance polyanionic electrode materials.
引用
收藏
页数：10
相关论文
共 40 条
[1]   NASICON-type air-stable and all-climate cathode for sodium-ion batteries with low cost and high-power density [J].
Chen, Mingzhe ;
Hua, Weibo ;
Xiao, Jin ;
Cortiel, David ;
Chen, Weihua ;
Wang, Enhui ;
Hu, Zhe ;
Gu, Qinfen ;
Wang, Xiaolin ;
Indris, Sylvio ;
Chou, Shu-Lei ;
Dou, Shi-Xue .
NATURE COMMUNICATIONS, 2019, 10 (1)
[2]   Challenges and Perspectives for NASICON-Type Electrode Materials for Advanced Sodium-Ion Batteries [J].
Chen, Shuangqiang ;
Wu, Chao ;
Shen, Laifa ;
Zhu, Changbao ;
Huang, Yuanye ;
Xi, Kai ;
Maier, Joachim ;
Yu, Yan .
ADVANCED MATERIALS, 2017, 29 (48)
[3]   Recent Advances for High-Entropy based Layered Cathodes for Sodium Ion Batteries [J].
Gao, Xudong ;
Zhang, Xiaoyu ;
Liu, Xiangyu ;
Tian, Yinfeng ;
Cai, Qiuyun ;
Jia, Min ;
Yan, Xiaohong .
SMALL METHODS, 2023, 7 (09)
[4]   Electrode Materials of Sodium-Ion Batteries toward Practical Application [J].
Huang, Yangyang ;
Zheng, Yuheng ;
Li, Xiang ;
Adams, Felix ;
Luo, Wei ;
Huang, Yunhui ;
Hu, Liangbing .
ACS ENERGY LETTERS, 2018, 3 (07) :1604-1612
[5]  
Jian Z., 2017, ADV MATER, V29, P20
[6]   Superior Electrochemical Performance and Storage Mechanism of Na3V2(PO4)3 Cathode for Room-Temperature Sodium-Ion Batteries [J].
Jian, Zelang ;
Han, Wenze ;
Lu, Xia ;
Yang, Huaixin ;
Hu, Yong-Sheng ;
Zhou, Jing ;
Zhou, Zhibin ;
Li, Jianqi ;
Chen, Wen ;
Chen, Dongfeng ;
Chen, Liquan .
ADVANCED ENERGY MATERIALS, 2013, 3 (02) :156-160
[7]   Carbon coated Na3V2(PO4)3 as novel electrode material for sodium ion batteries [J].
Jian, Zelang ;
Zhao, Liang ;
Pan, Huilin ;
Hu, Yong-Sheng ;
Li, Hong ;
Chen, Wen ;
Chen, Liquan .
ELECTROCHEMISTRY COMMUNICATIONS, 2012, 14 (01) :86-89
[8]   Polyanion-type cathode materials for sodium-ion batteries [J].
Jin, Ting ;
Li, Huangxu ;
Zhu, Kunjie ;
Wang, Peng-Fei ;
Liu, Pei ;
Jiao, Lifang .
CHEMICAL SOCIETY REVIEWS, 2020, 49 (08) :2342-2377
[9]   Electrospun NaVPO4F/C Nanofibers as Self-Standing Cathode Material for Ultralong Cycle Life Na-Ion Batteries [J].
Jin, Ting ;
Liu, Yongchang ;
Li, Yang ;
Cao, Kangzhe ;
Wang, Xiaojun ;
Jiao, Lifang .
ADVANCED ENERGY MATERIALS, 2017, 7 (15)
[10]   Improving the energy density of Na3V2(PO4)3-based positive electrodes through V/Al substitution [J].
Lalere, F. ;
Seznec, V. ;
Courty, M. ;
David, R. ;
Chotard, J. N. ;
Masquelier, C. .
JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (31) :16198-16205
1234